72039-82-8

Basic information

• Product Name: Silane, (6,10-dimethyl-5,9-undecadien-1-ynyl)trimethyl-, (E)-
• CAS NO: 72039-82-8
• Molecular Formula: C16H28Si
• Molecular Weight: 248.484
• Mol File: 72039-82-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Silane, (6,10-dimethyl-5,9-undecadien-1-ynyl)trimethyl-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (6,10-dimethyl-5,9-undecadien-1-ynyl)trimethyl-, (E)-(72039-82-8)
• EPA Substance Registry System: Silane, (6,10-dimethyl-5,9-undecadien-1-ynyl)trimethyl-, (E)-(72039-82-8)

Safety Data

• Hazardous Substances Data: 72039-82-8(Hazardous Substances Data)

Upstream product

• 6224-91-5 trimethyl(prop-1-ynyl)silane 
• 5389-87-7 1-chloro-3,7-dimethylocta-2,6-diene 
• 75-77-4 chloro-trimethyl-silane 
• 106-96-7 propargyl bromide 

Downstream Products

• 947688-24-6 C₂₈H₄₅ClO₂Si 
• 1173-76-8 ubiquinone Q₃ 
• 1379679-84-1 (3aS,7aS)-4,4,7a-trimethyloctahydro-1H-inden-1-one trisyl hydrazone 

Relevant articles and documents

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Total Synthesis of (-)-Chromodorolide B by a Computationally-Guided Radical Addition/Cyclization/Fragmentation Cascade

The first total synthesis of a chromodorolide marine diterpenoid is described. The core of the diterpenoid is constructed by a bimolecular radical addition/cyclization/fragmentation cascade that unites two complex fragments and forms two C-C bonds and four contiguous stereogenic centers of (-)-chromodorolide B in a single step. This coupling step is initiated by visible-light photocatalytic fragmentation of a redox-active ester, which can be accomplished in the presence of an iridium or a less-precious electron-rich dicyanobenzene photocatalyst, and employs equimolar amounts of the two addends. Computational studies guided the development of this central step of the synthesis and provide insight into the origin of the observed stereoselectivity.