72076-10-9Relevant academic research and scientific papers
Enantiomerically Pure Building Blocks from Sugars, 10 2,3-Dihydropyranones with Contiguous Chiral Centers: Practical Routes for Their Aquisition and Evaluation of their Reaction Potential
Lichtenthaler, Frieder W.,Nishiyama, Shigeru,Weimer, Thomas
, p. 1163 - 1170 (2007/10/02)
A practical, large-scale adaptable four-step procedure has been developed for the conversion of D-glucose into pyranoid enediolone esters with (R,R)-configuration in contiguous chiral centers, involving hydrolysis of the readily accessible bis-acetonide o
ANOMERIC STEREOCONTROL IN ADDITION REACTIONS TO HEXOSE-DERIVED DIHYDROPYRANONES
Lichtenthaler, Frieder W.,Nishiyama, Shigeru,Koehler, Peter,Lindner, Hans J.
, p. 13 - 26 (2007/10/02)
The outcome of base-catalysed O- and C-nucleophile additions to the carbonyl group of benzoylated 4-deoxy-D-glycero-hex-3-enopyranosid-2-ulose (1) depends on the conditions used.With methanol / sodium iodide, methanol / sodium methoxide (traces), or methy
