72138-56-8Relevant academic research and scientific papers
Nickel-catalyzed cross-coupling of diphenylphosphine with vinyl bromides and chlorides as a route to diphenylvinylphosphines
Shulyupin, Mstilsav O.,Chirkov, Evgeniy A.,Kazankova, Marina A.,Beletskaya, Irina P.
, p. 658 - 660 (2005)
An efficient nickel-catalyzed reaction for the phosphination of vinyl bromides and chlorides was developed. The procedure uses a combination of up to 1 mol% of nickel acetylacetonate, triethylamine and dimethylformamide as a solvent. The double bond geometry of the vinyl halides was retained under the reaction conditions.
