72179-98-7

Upstream product

• 100-47-0 benzonitrile 
• 108-59-8 malonic acid dimethyl ester 

Downstream Products

• 72180-00-8 2-cyclohexyl-1,1-dioxo-5-phenyl-1,6-dihydro-2H-1λ⁶-[1,2,6]thiadiazin-3-one 
• 97652-63-6 2-(Hydroxy-phenyl-methylene)-malonic acid dimethyl ester 
• 72180-03-1 4-bromo-2-cyclohexyl-1,1-dioxo-5-phenyl-1,6-dihydro-2H-1λ⁶-[1,2,6]thiadiazin-3-one 
• 72179-99-8 2-isopropyl-1,1-dioxo-5-phenyl-1,6-dihydro-2H-1λ⁶-[1,2,6]thiadiazin-3-one 

Relevant academic research and scientific papers

Regioselective Synthesis of Pyrimidines from Ketene Dithioacetals or Alkoxymethylene Compounds

Regioselective cyclizations of the condensation products obtained by the reaction of nitrogen nucleophiles with ketene dithioacetals or alkoxymethylene compounds are reported.Stereoelectronic factors or geometry of the carbon-carbon double bond determine

PREPARATION OF α,β-DEHYDRO-β-AMINO ACID DERIVATIVES BY TIN-PROMOTED ADDITION OF MALONATES TO SIMPLE NITRILES.

Simple alyphatic and aromatic nitriles undergo reaction with malonate esters in the presence of tin(lV) chloride to give derivatives of a α,β-dehydro-β-amino acids.The same products are obtained through use of bromomalonateesters.