7218-17-9Relevant academic research and scientific papers
Experimental and computational studies on the [3,3]- and [3,5]-sigmatropic rearrangements of acetoxycyclohexadienones: A non-ionic mechanism for acyl migration
Sharma, Shikha,Rajale, Trideep,Cordes, David B.,Hung-Low, Fernando,Birney, David M.
supporting information, p. 14438 - 14447 (2013/10/21)
Flash vacuum pyrolysis studies of substituted 6-acetoxy-2,4- cyclohexadienones (3 and 10) from 300 to 500 C provide strong experimental evidence that direct [3,5]-sigmatropic rearrangements in these molecules are favored over the more familiar [3,3]-sigma
A solvolytic C-C cleavage reaction of 6-acetoxycyclohexa-2,4-dienones: Mechanistic implications for the intradiol catechol dioxygenases
Eley,Crowley,Bugg
, p. 2091 - 2097 (2007/10/03)
6-Acetoxycyclohexa-2,4-dienones are found to undergo a rapid reaction in methanol/water under mildly basic conditions to give an acyclic ketoester as the major product for 6-phenyl and 6-methyl substrates. Reaction monitoring by UV spectroscopy indicates
