721968-93-0

Upstream product

• 150-19-6 O-methylresorcine 
• 2937-50-0 Allyl chloroformate 

Downstream Products

• 917377-78-7 (S)-(+)-2-phenylindoline 
• 293737-30-1 (R)-indoline-2-carboxylic acid methyl ester 
• 1061617-43-3 methyl (S)-N-(allyloxycarbonyl)indoline-2-carboxylate 
• 141410-06-2 (S)-indoline-2-carboxylic acid methyl ester 
• 37592-19-1 3-allyloxyanisole 
• 1775-86-6 (+)-(2S,3S)-cis-5,6,7,8,8a,9-hexahydro-4bH-carbazole 
• 1398382-73-4 allyl (4aR,9aR)-1,2,3,4,4a,9a-hexahydro-9H-carbazole-9-carboxylate 
• 1398382-77-8 allyl (2S,3R)-3-methyl-2-phenylindoline-1-carboxylate 
• 1398383-12-4 (2R,3S)-3-methyl-2-phenylindoline 
• 1582815-25-5 (1S,2R)-N-(2-amino-1,2-diphenylethyl)allyl carbamate 

Relevant academic research and scientific papers

Enzymatic resolution of a secondary amine using novel acylating reagents

Phenyl allylcarbonates are useful acylating agents for the enzymatic resolution of 1-methyl tetrahydroisoquinoline.

Regioselective iron-catalyzed decarboxylative allylic etherification

[Chemical Equation Presented] An anionic iron complex catalyzes the decarboxylative allylation of phenols to form allylic ethers in high yield. The allylation is regioselective rather than regiospecific. This suggests that the allylation proceeds through π-allyl iron intermediates in contrast to related allylations of carbon nucleophiles that have been proposed to proceed via π-allyl complexes. Ultimately, iron catalysts have the potential to replace more expensive palladium catalysts that are typically utilized for decarboxylative couplings.