72206-42-9

Basic information

• Product Name: a-D-Glucofuranose,1,2-O-cyclohexylidene-3-O-(phenylmethyl)-, bis(diphenylphosphinite) (9CI)
• Synonyms: Spiro[cyclohexane-1,2'-furo[2,3-d][1,3]dioxole],a-D-glucofuranose deriv.;Glucophinite
• CAS NO: 72206-42-9
• Molecular Formula: C43H44 O6 P2
• Molecular Weight: 718.766
• Mol File: 72206-42-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: a-D-Glucofuranose,1,2-O-cyclohexylidene-3-O-(phenylmethyl)-, bis(diphenylphosphinite) (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: a-D-Glucofuranose,1,2-O-cyclohexylidene-3-O-(phenylmethyl)-, bis(diphenylphosphinite) (9CI)(72206-42-9)
• EPA Substance Registry System: a-D-Glucofuranose,1,2-O-cyclohexylidene-3-O-(phenylmethyl)-, bis(diphenylphosphinite) (9CI)(72206-42-9)

Safety Data

• Hazardous Substances Data: 72206-42-9(Hazardous Substances Data)

Upstream product

• 13322-89-9 3-O-Benzyl-1,2-O-cyclohexylidene-α-D-glucofuranose 
• 1079-66-9 chloro-diphenylphosphine 

Relevant articles and documents

Chiral Phosphinites Derived from α-D-Glucofuranose and α-L-Idofuranose. A Comparison to Chiral Phosphines in Asymmetric Hydrogenation

Two chiral phosphinites and two chiral phosphines, which are derivatives of α-D-glucofuranose and α-L-idofuranose, were prepared and used as ligands in rhodium-catalyzed asymmetric hydrogenations.Six substrates were studied.Unlike phosphinites prepared from α-D-glucopyranose, the phosphinites prepared in this study were effective in inducing asymmetry in the hydrogenations of atropic acid and α-methylcinnamic acid.The phosphinites were frequently better chiral modifiers than phosphines when an acetamido group was not present in the substrate.