13322-89-9

Upstream product

• 100-39-0 benzyl bromide 
• 23397-76-4 1,2:5,6-di-O-cyclohexylidene-α-D-glucofuranose 

Downstream Products

• 72206-42-9 Glucophinite 
• 71069-26-6 3-O-Benzyl-1,2-O-cyclohexylidene-α-D-glucofuranose Ditosylate 
• 72206-43-0 3-O-Benzyl-1,2-O-cyclohexylidene-α-L-idofuranose 
• 72206-45-2 3-O-Benzyl-1,2-O-cyclohexylidene-α-l-idofuranose Ditosylate 
• 72206-44-1 Idophinite 
• 748793-13-7 (3S,3aR,4R,5S,6S,6aS)-1-Benzyl-5-benzyloxy-4,6-dihydroxy-3-methyl-hexahydro-cyclopenta[c]isoxazole-3-carboxylic acid ethyl ester 
• 15354-75-3 3-O-benzyl-1,2-O-cyclohexylidene-α-D-xylo-pentodialdo-1,4-furanose 

Relevant academic research and scientific papers

Nascent-HBr-Catalyzed Removal of Orthogonal Protecting Groups in Aqueous Surfactants

Organic reactions in the aqueous environment have recently emerged as a promising research area. The generation of nascent-HBr from the slow hydrolysis of the dispersed catalyst, benzyl bromide, with the interior water present in the hydrophobic core of the confined micellar medium in aqueous surfactant is described for the first time. The sustained-release nascent-HBr enabled the chemoselective cleavages of acid-sensitive orthogonal functionalities present in carbohydrates, amino alcohols, and hydroxylated acyclic compounds in good to excellent yields.

[3+2] Cycloaddition reactions: A simple entry to the 1-aza-2-oxo-3,4,5,6- tetrahydroxybicyclo[3.3.0]octane ring system

The [3+2] intramolecular nitrone cycloaddition (INC) reaction on appropriately designed olefinic nitrones derived from D-glucose, having the nitrone at C-1 and α,β-unsaturated ester functionalities at C-5 of the sugar backbone, afforded the isoxazolidine