72247-99-5Relevant articles and documents
Silver(I) o-Nitrobenzoate
Jaber, Farouk,Charbonnier, Francois,Faure, Rene,Gebicki, Krzysztof
, p. 1444 - 1447 (1994)
The title compound, , was obtained from silver nitrate and 2-nitrobenzoic acid in aqueous solution.The crystal comprises a threedimensional polymeric network with short Ag--Ag distances .All three Ag atoms of the asymmetric unit are included in eightmembered rings (Ag--O--C--O)2 with two types of coordination: (a) a trigonal bipyramidal arrangement (for one Ag atom of the asymmetric unit), the Ag atom being linked to another Ag atom and to four O atoms , and (b) a tetrahedral arrangement (for two Ag atoms of the asymmetric unit), where each Ag atom is linked to another and to three O atoms .Moreover, the o-nitrobenzoato ligands show three different conformations induced by the coordination modes, with rotations of the NO2 and CO2 groups, resulting in all the atoms of each ligand not being located in the same plane.
A Predictive Model for the Decarboxylation of Silver Benzoate Complexes Relevant to Decarboxylative Coupling Reactions
Crovak, Robert A.,Hoover, Jessica M.
supporting information, p. 2434 - 2437 (2018/02/28)
Decarboxylative coupling reactions offer an attractive route to generate functionalized arenes from simple and readily available carboxylic acid coupling partners, yet they are underutilized due to limitations in the scope of carboxylic acid coupling partner. Here we report that the field effect parameter (F) has a substantial influence on the rate of decarboxylation of well-defined silver benzoate complexes. This finding provides the opportunity to surpass current substrate limitations associated with decarboxylation and to enable widespread utilization of decarboxylative coupling reactions.