72247-99-5

Usage

Uses

Used in Organic Synthesis:
Silver(I) o-nitrobenzoate is used as a reagent in organic synthesis for various chemical reactions, such as the formation of carbon-carbon bonds and the synthesis of complex organic molecules.
Used in Catalyst Applications:
Silver(I) o-nitrobenzoate is used as a catalyst to accelerate and improve the efficiency of various chemical reactions, including oxidation, reduction, and coupling reactions.
Used in Antibacterial and Antifungal Applications:
Silver(I) o-nitrobenzoate has been studied for its potential antibacterial and antifungal properties, making it a candidate for use in the development of new antimicrobial agents.
Used in Material Science:
Silver(I) o-nitrobenzoate has been investigated for its potential use in the development of new materials, such as conductive polymers and sensors, due to its unique properties.
Used in Pharmaceutical Development:
Silver(I) o-nitrobenzoate is of interest in the field of chemistry for its potential applications in the development of new pharmaceuticals, given its diverse chemical properties and reactivity.

Upstream product

• 552-16-9 ortho-nitrobenzoic acid 
• 20667-12-3 silver(l) oxide 

Downstream Products

• 577-19-5 2-nitrophenyl bromide 
• 54900-07-1 1,2-bis-(2-nitro-benzoyloxy)-ethane 
• 2436-96-6 1-nitro-2-(2-nitrophenyl)benzene 
• 98-95-3 nitrobenzene 

Relevant academic research and scientific papers

Silver(I) o-Nitrobenzoate

The title compound, , was obtained from silver nitrate and 2-nitrobenzoic acid in aqueous solution.The crystal comprises a threedimensional polymeric network with short Ag--Ag distances .All three Ag atoms of the asymmetric unit are included in eightmembered rings (Ag--O--C--O)2 with two types of coordination: (a) a trigonal bipyramidal arrangement (for one Ag atom of the asymmetric unit), the Ag atom being linked to another Ag atom and to four O atoms , and (b) a tetrahedral arrangement (for two Ag atoms of the asymmetric unit), where each Ag atom is linked to another and to three O atoms .Moreover, the o-nitrobenzoato ligands show three different conformations induced by the coordination modes, with rotations of the NO2 and CO2 groups, resulting in all the atoms of each ligand not being located in the same plane.

Gold Catalyzed Decarboxylative Cross-Coupling of Iodoarenes

This report details a decarboxylative cross-coupling of (hetero)aryl carboxylates with iodoarenes in the presence of a gold catalyst (>25 examples, up to 96% yield). This reaction is site specific, which overcomes prior limitations associated with gold catalyzed oxidative coupling reactions. The reactivity of the (hetero)aryl carboxylate correlates qualitatively to the field effect parameter (Fortho). Reactions with isolated gold complexes and DFT calculations support a mechanism proceeding through oxidative addition at a gold(I) cation with decarboxylation being viable at either a gold(I) or a silver(I) species.

A Predictive Model for the Decarboxylation of Silver Benzoate Complexes Relevant to Decarboxylative Coupling Reactions

Decarboxylative coupling reactions offer an attractive route to generate functionalized arenes from simple and readily available carboxylic acid coupling partners, yet they are underutilized due to limitations in the scope of carboxylic acid coupling partner. Here we report that the field effect parameter (F) has a substantial influence on the rate of decarboxylation of well-defined silver benzoate complexes. This finding provides the opportunity to surpass current substrate limitations associated with decarboxylation and to enable widespread utilization of decarboxylative coupling reactions.