72248-86-3

Upstream product

• 63404-83-1 6-methyl-4-phenylpyridin-2(1H)-one 
• 74-88-4 methyl iodide 
• 15031-43-3 1,6-dimethylpyridin-2(1H)-one 
• 108-86-1 bromobenzene 

Downstream Products

• 72248-88-5 dimethyl 1,2-dimethyl-3-oxo-5-phenyl-2-azabicyclo<2.2.2>octa-5,7-diene-7,8-dicarboxylate 
• 83021-73-2 (1R,8R)-8,9-Dimethyl-11-phenyl-9-aza-tricyclo[6.2.2.0^2,7]dodeca-2⁽⁷⁾,3,5,11-tetraen-10-one 
• 83021-73-2 (1S,8S)-8,9-Dimethyl-11-phenyl-9-aza-tricyclo[6.2.2.0^2,7]dodeca-2,4,6,11-tetraen-10-one 

Relevant academic research and scientific papers

Iridium-Catalyzed Site-Selective C-H Borylation of 2-Pyridones

An iridium-catalyzed site-selective C-H borylation of 2-pyridones has been developed. The site selectivity is predominantly controlled by steric factors, and we can access C4, C5, and C6 C-H on the 2-pyridone ring by the judicious choice of ligand and sol

DEILS-ALDER ADDUCTS FROM N-SUBSTTITUED TAUTOMERIC 2(1H)-PYRIDONE-2-HYDROXYPYRIDINES; 5,6-BENZO-AZABARRELENONES AND 5,6-BENZO-AZABARRELENES

Diels-Alder reactions of several N-unsubstitued tautomeric 2(1H)-pyridone-2-hydroxypyridines with benzyne were examined and found to afford 5,6-azabarrelenones, wich were converted to hitherto unknown 5,6-benzo-azabarrelenes.

Preparation and Reaction of Pyridones: Steric and Electronic Effects on Cycloadditions with 2(1H)-Pyridones

The reactions of series of substituted 2(1H)-pyridones with dimethyl butynedioate have been studied.Cycloadditions across the 3,6-positions can be observed in certain instances and are particularly favoured where steric buttressing occurs between the substituent groups of the starting pyridones.The pyridone could not be induced to react with simple olefins, either by intermolecular or, via incorporation of alkenyl substituents, by intramolecular processes.From the results it is shown that 2-pyridones can be encouraged to behave as reactive classical dienes in cycloaddition reactions.