72269-48-8

Usage

Uses

Used in Agricultural Industry:
LYCOPERSILURE is used as a biological control agent for the purpose of managing pest populations that threaten tomato crops. By attracting male insects with its pheromone blend, it prevents mating with females, thereby disrupting the pests' reproductive cycle and reducing their overall numbers.
Used in Environmental Protection:
LYCOPERSILURE is used as an environmentally friendly alternative to chemical pesticides, helping to minimize the environmental impact of pest control measures and supporting sustainable pest management practices in agriculture.

InChI:InChI=1/C15H28O2/c1-3-4-5-6-7-8-9-10-11-12-13-14-17-15(2)16/h10-11H,3-9,12-14H2,1-2H3/b11-10+

Upstream product

• 74744-28-8 1-undecen-3-yne 
• 1426946-85-1 ethyl (4E)-5-chloropent-4-enoate 
• 84200-37-3 (E)-diethyl (but-2-en-1-yl)malonate 
• 129908-60-7 tridec-5-en-4-olide 
• 129908-61-8 tridec-5Z-en-4-olide 
• 35329-59-0 tridec-4E-enoic acid 
• 62936-19-0 1-bromo-3E-dodecene 
• 139269-67-3 (E)-7-bromohept-4-en-1-ol 
• 147588-64-5 1-cyclopropylbutane-1,4-diol 
• 25979-84-4 1-cyclopropyl-4-hydroxybutan-1-one 
• 75568-02-4 (4E)-tridec-4-en-1-ol 
• 75-36-5 acetyl chloride 
• 76853-04-8 (E)-1-Acetoxy-4-tridecene Oxide 
• 108-24-7 acetic anhydride 

Relevant academic research and scientific papers

Fe-catalyzed synthesis of (4E)-tridec-4-en-1-yl acetate, sex pheromone of tomato pinworm (Keiferia lycopersicella)

Starting with industrially available 1,3-dichloropropene a stereoselective process was developed for the preparation of (4E)-tridec-4-en-1-yl acetate, sex pheromone of tomato pinworm (Keiferia lycopersicella) using in the key stage the Fe-catalyzed cross-coupling of ethyl (4E)-5-chloropent-4-enoate with octylmagnesium bromide.

ALKYLATION OF ACETYLCYCLOPROPANE CYCLOHEXYLIMINE BY ETHYLENE OXIDE DERIVATIVES AS A KEY STEP IN THE SYNTHESIS OF SOME INSECT ACETOGENIN PHEROMONES

The interaction of Li derivatives of acetylcyclopropane cyclohexylimine with ethylene, propylene, and isoprene oxides leads efficiently to the corresponding γ-cyclopropylketols.The cyclopropylcarbinol corresponding to the first of them is smoothly converted under the action of the couple Me3SiBr/ZnBr2 to a linear E-C7-homoallyl bromide, which is then used in the stereocontrolled synthesis of tridec-4E-enyl and trideca-4E,7Z-dienyl acetates - components of the sex pheromones of some Lepidoptera species.Keywords: acetylcyclopropane, insect acetogenin pheromones, homoallyl rearrangement, Julia olefination, olefin oxides.

Acetylcyclopropane as a Five-Carbon Building Block in the Synthesis of some Acetogenin Insect Pheromones

Interaction of deprotonated acetylcyclopropane cyclohexylimine with several aliphatic alkyl halides, epoxides, and aldehydes efficiently gave the corresponding cyclopropyl ketones.Some of the respectible alcohols were rearranged in a highly stereoselective manner under the action of trimethylsilyl bromide in the presence of zinc bromide into the corresponding linear (E)-homoallyl bromides.The latter were used, in turn, as key intermediates in concise syntheses of thirteen terminally functionalized straight-chain oligoolefins which are known to constitute acetogenin pheromonal components for more than 65 species of lepidopteran insects.

LOW-MOLECULAR-MASS BIOREGULATORS. III. SYNTHESIS OF TRIDEC-4E-ENYL ACETATE-THE SEX PHEROMONE OF Keiferia lycopersicella

A new method has been developed for the synthesis of tridec-4E-enyl acetate - the sex pheromone of the tomato pinworm Keiferia lycopersicella.