72328-14-4

Basic information

• Product Name: trans-3,6-bis(3-benzoylpropyl)-1,2,4,5-tetroxane
• Synonyms: trans-3,6-bis(3-benzoylpropyl)-1,2,4,5-tetroxane
• CAS NO: 72328-14-4
• Molecular Weight: 384.429
• Mol File: 72328-14-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-3,6-bis(3-benzoylpropyl)-1,2,4,5-tetroxane(CAS DataBase Reference)
• NIST Chemistry Reference: trans-3,6-bis(3-benzoylpropyl)-1,2,4,5-tetroxane(72328-14-4)
• EPA Substance Registry System: trans-3,6-bis(3-benzoylpropyl)-1,2,4,5-tetroxane(72328-14-4)

Safety Data

• Hazardous Substances Data: 72328-14-4(Hazardous Substances Data)

Upstream product

• 72328-15-5 cis-3,6-bis(3-benzoylpropyl)-1,2,4,5-tetroxane 
• 23253-31-8 1-phenylcyclopentene ozonide 
• 72328-16-6 3,5-dipentyl-1,2,4-trioxolan 
• 20463-40-5 1-methyl-6,7,8-trioxabicyclo[3.2.1]octane 

Downstream Products

• 75424-63-4 5-oxo-5-phenylpentanal 
• 1501-05-9 5-oxo-5-phenylvaleric acid 

Relevant articles and documents

Reaction of 1,2,4,5-Tetroxan with Antimony Pentachloride or Liquid Sulphur Dioxide: Heterolytic Fission of Carbon-Oxygen or Oxygen-Oxygen Bonds

The reactions of 11 kinds of tetroxans with antimony pentachloride have been investigated.A mixture of ketone (aldehyde) and ester (carboxylic acid) was obtained, the ratio of which was found to depend on the substituents.In the presence of the catalyst cis-3,6-bis(3-benzoylpropyl)-1,2,4,5-tetroxan rearranges to the trans-isomer.In the reaction of some tetroxans with liquid sulphur dioxide, a mixture of ester and ketone was obtained in a molar ratio of 1:1.Reductive ozonolysis of some alkenes in the presence of 10 mol equiv. of sulphur dioxide in methylene chloride gave the corresponding carbonyl compounds in good yields.