72346-35-1Relevant academic research and scientific papers
Proof of a Radical Transannular Hydrogen Migration in the Longifolene Series
Boivin, J.,Silva, E. da,Ourisson, G.,Zard, S. Z.
, p. 2501 - 2504 (1990)
Radical decarboxylation of isolongifolic acid 3a affords in good yield the thio-ether 4 through a reaction involving a clean 1,5-transannular hydrogen shift.The thio-ether 4 was further converted in almost quantitative yield into the olefin 7 through sequential oxidation-elimination.
