72360-60-2Relevant academic research and scientific papers
Rapid Hemiacetal Formation from a Simple, Open-chain Monothioacetal during Soft Metal Ion-promoted Hydrolysis
Penn, David,Satchell, Derek P. N.
, p. 54 - 55 (1982)
The Hg2+- and Tl3+-promoted hydrolyses of the monothioacetal α-ethoxy-α-ethylthiotoluene (1) proceed via the relatively very rapid formation of the hemiacetal (2) whose subsequent hydrolysis controls the observed rate of aldehyde formation.
A convenient one-pot synthesis of α-isothiocyanatoethers and unusual course of some of its nucleophilic displacement reactions
Bernat, Juraj,Kristian, Pavol,Guspanova, Jana,Imrich, Jan,Busova, Tatiana
, p. 1491 - 1496 (1997)
A simple new method has been devised for the preparation of α-isothiocyanatoethers 1a-1f in good yields by reaction of PO(NCS)3 or (PhO)2PONCS with an equimolar mixture of aldehydes and alcohols. The course of nucleophilic additions of methanol, amines and hydrazine to 1a-1f is described.
