72369-93-8

Upstream product

• 116306-89-9 (3αR,5S,6αR)-5-(benzyloxymethyl)-2,2-dimethyl-tetrahydrofuro[2,3-d][1,3]dioxole 
• 3396-71-2 3-deoxy-1,2-O-isopropylidene-α-D-ribofuranose 
• 4613-68-7 O¹,O²-isopropylidene-α-D-erythro-3-deoxy-pentodiald-1,4-ose 
• 114861-25-5 (3R,5S)-5-(benzyloxymethyl)tetrahydrofuran-2,3-diol 

Downstream Products

• 178860-74-7 (2S,4R)-2,4-((S)-benzylidenedioxy)-1-benzyloxy-16-methylheptadec-5(E/Z)-ene 
• 178860-73-6 ((2R,4R,6S)-6-Benzyloxymethyl-2-phenyl-[1,3]dioxan-4-ylmethoxy)-tert-butyl-diphenyl-silane 
• 178860-81-6 (2R,4S)-2,4-((R)-benzylidenedioxy)-5-benzyloxypentanal 
• 178860-80-5 (2R,4S)-2,4-((R)-benzylidenedioxy)-1-benzyloxy-5-hydroxypentane 
• 178860-79-2 (2R,4S)-1-Benzyloxy-5-(tert-butyl-diphenyl-silanyloxy)-pentane-2,4-diol 

Relevant academic research and scientific papers

Revised structure and synthesis of flavolipin

The proposed structure of natural flavolipin was revised as N-[N-[(3R)- 15-methyl-3-(13-methyltetradecanoyloxy)hexadecanoyl]glycyl]-L-serine as a result of a synthetic study and biological activity tests, and its isomers synthesized in a stereocontrolled manner.

Stereocontrolled synthesis of all stereoisomers of the proposed flavolipin

All four stereoisomers of flavolipin were synthesized from D-glucose in a stereocontrolled manner. None of them was identical with the reported natural product.