724765-06-4

Upstream product

• 83458-93-9 (3S)-6-(Benzyloxy)hexane-1,3-diol 
• 127793-67-3 (S)‐7‐(benzyloxy)hept‐1‐en‐4‐ol 
• 5470-84-8 4-benzyloxybutanal 
• 4541-14-4 4-benzyloxy-butan-1-ol 
• 151-50-8 potassium cyanide 

Downstream Products

• 724765-29-1 C₅₀H₈₈NO₁₃PSi₂ 
• 724765-14-4 C₅₀H₉₀NO₁₃PSi₂ 
• 724765-27-9 {3-[6-[5-[6-(1-benzyloxymethyl-propyl)-4-cyano-2,2-dimethyl-[1,3]dioxan-4-yl]-2-(tert-butyl-dimethyl-silanyloxy)-pentyl]-4-(tert-butyl-dimethyl-silanyloxy)-6-methoxy-3-vinyl-tetrahydro-pyran-2-yl]-2-hydroxy-propyl}-phosphonic acid diethyl ester 
• 724765-28-0 [2-[5-[6-(1-benzyloxymethyl-propyl)-4-cyano-2,2-dimethyl-[1,3]dioxan-4-yl]-2-(tert-butyl-dimethyl-silanyloxy)-pentyl]-4-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-5-oxo-hexahydro-pyrano[4,3-b]pyran-7-ylmethyl]-phosphonic acid diethyl ester 
• 724765-13-3 [2-[5-[6-(1-benzyloxymethyl-propyl)-4-cyano-2,2-dimethyl-[1,3]dioxan-4-yl]-2-(tert-butyl-dimethyl-silanyloxy)-pentyl]-4-(tert-butyl-dimethyl-silanyloxy)-5-hydroxy-2-methoxy-hexahydro-pyrano[4,3-b]pyran-7-ylmethyl]-phosphonic acid diethyl ester 
• 724765-26-8 (4R,6R)-6-((R)-1-Benzyloxymethyl-propyl)-4-{(S)-4-(tert-butyl-dimethyl-silanyloxy)-5-[(2R,4S,5S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-(2,3-dihydroxy-propyl)-2-methoxy-5-vinyl-tetrahydro-pyran-2-yl]-pentyl}-2,2-dimethyl-[1,3]dioxane-4-carbonitrile 
• 724764-98-1 (4R,6R)-4-[(S)-5-[(2R,4S,5S,6S)-6-Allyl-4-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-5-vinyl-tetrahydro-pyran-2-yl]-4-(tert-butyl-dimethyl-silanyloxy)-pentyl]-6-((R)-1-benzyloxymethyl-propyl)-2,2-dimethyl-[1,3]dioxane-4-carbonitrile 
• 724765-12-2 (4R,6R)-6-((R)-1-Benzyloxymethyl-propyl)-4-{(S)-4-(tert-butyl-dimethyl-silanyloxy)-5-[(2R,4S,5S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-6-(2-oxo-ethyl)-5-vinyl-tetrahydro-pyran-2-yl]-pentyl}-2,2-dimethyl-[1,3]dioxane-4-carbonitrile 
• 724765-24-6 (2R,4S,5S,6S)-6-Allyl-2-[(S)-5-benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-pentyl]-4-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-5-vinyl-tetrahydro-pyran 
• 724765-09-7 (4S,6S)-4-((4S,5S,6S)-6-Allyl-2,2-dimethyl-5-vinyl-[1,3]dioxan-4-ylmethyl)-6-(3-benzyloxy-propyl)-2,2-dimethyl-[1,3]dioxane-4-carbonitrile 
• 724765-10-0 (2R,4S,5R,6S)-6-Allyl-2-((S)-5-benzyloxy-2-hydroxy-pentyl)-5-vinyl-tetrahydro-pyran-2,4-diol 
• 724765-23-5 (2R,4S,5R,6S)-6-Allyl-2-((S)-5-benzyloxy-2-hydroxy-pentyl)-2-methoxy-5-vinyl-tetrahydro-pyran-4-ol 
• 724765-08-6 (S)-6-(3-Benzyloxy-propyl)-2,2-dimethyl-[1,3]dioxane-4-carbonitrile 

Relevant academic research and scientific papers

Synthesis of rimocidinolide methyl ester, the aglycone of (+)-rimocidin

An efficient, convergent route based on cyanohydrin acetonide couplings was used for the synthesis of the aglycone of rimocidin, rimocidinolide methyl ester (1). Cyanohydrin acetonides were used as β-hydroxyketone synthetic equivalents in the assembly of the polyol chain.