724765-13-3

Upstream product

• 724765-26-8 (4R,6R)-6-((R)-1-Benzyloxymethyl-propyl)-4-{(S)-4-(tert-butyl-dimethyl-silanyloxy)-5-[(2R,4S,5S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-(2,3-dihydroxy-propyl)-2-methoxy-5-vinyl-tetrahydro-pyran-2-yl]-pentyl}-2,2-dimethyl-[1,3]dioxane-4-carbonitrile 
• 724764-98-1 (4R,6R)-4-[(S)-5-[(2R,4S,5S,6S)-6-Allyl-4-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-5-vinyl-tetrahydro-pyran-2-yl]-4-(tert-butyl-dimethyl-silanyloxy)-pentyl]-6-((R)-1-benzyloxymethyl-propyl)-2,2-dimethyl-[1,3]dioxane-4-carbonitrile 
• 724765-12-2 (4R,6R)-6-((R)-1-Benzyloxymethyl-propyl)-4-{(S)-4-(tert-butyl-dimethyl-silanyloxy)-5-[(2R,4S,5S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-6-(2-oxo-ethyl)-5-vinyl-tetrahydro-pyran-2-yl]-pentyl}-2,2-dimethyl-[1,3]dioxane-4-carbonitrile 
• 724765-24-6 (2R,4S,5S,6S)-6-Allyl-2-[(S)-5-benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-pentyl]-4-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-5-vinyl-tetrahydro-pyran 
• 724765-11-1 (2R,4S,5S,6S)-6-Allyl-4-(tert-butyl-dimethyl-silanyloxy)-2-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-5-iodo-pentyl]-2-methoxy-5-vinyl-tetrahydro-pyran 
• 724765-25-7 (S)-5-[(2R,4S,5S,6S)-6-Allyl-4-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-5-vinyl-tetrahydro-pyran-2-yl]-4-(tert-butyl-dimethyl-silanyloxy)-pentan-1-ol 
• 724765-09-7 (4S,6S)-4-((4S,5S,6S)-6-Allyl-2,2-dimethyl-5-vinyl-[1,3]dioxan-4-ylmethyl)-6-(3-benzyloxy-propyl)-2,2-dimethyl-[1,3]dioxane-4-carbonitrile 
• 724765-19-9 (S)-4-Benzyl-3-[(2S,3R)-2-ethyl-3-hydroxy-5-(4-methoxy-benzyloxy)-pentanoyl]-oxazolidin-2-one 
• 724765-10-0 (2R,4S,5R,6S)-6-Allyl-2-((S)-5-benzyloxy-2-hydroxy-pentyl)-5-vinyl-tetrahydro-pyran-2,4-diol 
• 724765-23-5 (2R,4S,5R,6S)-6-Allyl-2-((S)-5-benzyloxy-2-hydroxy-pentyl)-2-methoxy-5-vinyl-tetrahydro-pyran-4-ol 
• 724765-21-3 (3R,4R)-4-Benzyloxymethyl-1-(4-methoxy-benzyloxy)-hexan-3-ol 
• 724765-00-8 (2R,3S,4S)-1-Triisopropylsilanyloxy-3-vinyl-hept-6-ene-2,4-diol 
• 724765-17-7 (R)-3-((R)-1-Hydroxy-2-triisopropylsilanyloxy-ethyl)-hepta-1,6-dien-4-one 
• 724765-20-2 (2S,3R)-2-Ethyl-3-hydroxy-5-(4-methoxy-benzyloxy)-pentanoic acid 

Downstream Products

• 724765-28-0 [2-[5-[6-(1-benzyloxymethyl-propyl)-4-cyano-2,2-dimethyl-[1,3]dioxan-4-yl]-2-(tert-butyl-dimethyl-silanyloxy)-pentyl]-4-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-5-oxo-hexahydro-pyrano[4,3-b]pyran-7-ylmethyl]-phosphonic acid diethyl ester 
• 724765-14-4 C₅₀H₉₀NO₁₃PSi₂ 
• 724765-29-1 C₅₀H₈₈NO₁₃PSi₂ 

Relevant academic research and scientific papers

Synthesis of rimocidinolide methyl ester, the aglycone of (+)-rimocidin

An efficient, convergent route based on cyanohydrin acetonide couplings was used for the synthesis of the aglycone of rimocidin, rimocidinolide methyl ester (1). Cyanohydrin acetonides were used as β-hydroxyketone synthetic equivalents in the assembly of the polyol chain.