7251-30-1Relevant academic research and scientific papers
Syntheses of the Terpenoid Precursors Cyclopent-2-enone and Cyclohex-2-enone Diesters
Kadas, I.,Morvai, V.,Arvai, G.,Toeke, L.,Szoelloesy, A.,et al.
, p. 107 - 118 (2007/10/02)
Two reaction pathways were elaborated for the practical and convenient syntheses of the title compounds.The first route applies a bromination-dehydrobromination sequence to introduce the double bond into 1-alkoxycarbonyl-2-oxocycloalkylacetic and propioni
Surface-mediated Solid-phase Reaction. Part 2. Highly Selective Mono- and Di-C-alkylation of 1,3-Dicarbonyl Compounds on the Surface of Alumina
Ranu, Brindaban C.,Bhar, Sanjay
, p. 365 - 368 (2007/10/02)
Highly selective mono- and di-C-alkylation of 1,3-dicarbonyl compounds with different, structurally varied alkyl halides has been achieved in high yields through a simple solvent-free reaction on the surface of alumina impregnated with sodium or potassium alkoxide.
CATALYST DEPENDENT MECHANISTIC PATHS IN THE REACTIONS OF ETHYL DIAZOACETATE WITH β-KETO ESTERS
Lottes, Andrew C.,Landgrebe, John A.,Larsen, Kristin
, p. 4093 - 4096 (2007/10/02)
The catalyzed decomposition of ethyl diazoacetate in the presence of β-keto esters produces regioisomeric enol ethers and the diester from formal carbenoid insertion into the α-C-H bond.The product distribution is very catalyst dependent.
