7253-07-8Relevant articles and documents
Blue fluorescent host compound, and preparation method and device thereof
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Paragraph 0076-0079, (2020/01/12)
The invention relates to a blue fluorescent host compound, and a preparation method and a device thereof. The structural formula of the blue fluorescent host compound is represented by chemical formula 1 shown in the description. Compared with a conventional material, the blue fluorescent host compound of the invention has the advantages of excellent electroluminescent properties, long device service life and proper color coordinates. The organic light-emitting device prepared from the blue fluorescent host compound adopts the novel compound of the chemical formula 1, so that the device becomes the organic light-emitting device with a high efficiency and a long service life. The preparation method of the blue fluorescent host compound has the advantages of simple process and high yield.
A comprehensive study of substituent effects on poly(dibenzofulvene)s
Wong, Michael Y.,Leung, Louis M.
, p. 512 - 520 (2017/02/05)
We herein report the first cross comparison of 14 poly(dibenzofulvene) derivatives (13 novel examples and the parent poly(dibenzofulvene)) in order to understand how the choice of substituent affects the physical properties of this interesting class of semiconducting polymers. Electron withdrawing substituents decreased the polymerization reactivity and resulted in very low molecular-weight products. Di-substituted poly(dibenzofulvene)s were found to be much less soluble than the mono-analogues which can be explained by the Hansen solubility parameter system. Analysis based on absorption, emission and electrochemistry profiles suggests that polymer solubility is a very important factor that controls the degree of stacking present in the polymer due to synthetic issues. For the first time, the thermal analysis of the parent poly(dibenzofulvene) and its derivatives is reported and it was believed that depolymerization occurred much earlier than the melting transition. We have also demonstrated the orthogonal synthesis of dibenzofulvene monomers using three distinct routes (lithiation, oxidation and Wittig) to cope with functional group compatibility.
A facile approach to the synthesis of substituted dibenzofulvenes-precursors to pi-stacked poly(dibenzofulvene)s
Wong, Michael Y.,Leung, Louis M.
experimental part, p. 3973 - 3977 (2010/07/04)
A series of novel substituted (2-methoxy, 2-nitro, 2-bromo, 2-iodo, 2-cyano, and 2-acetyl) and disubstitiuted (2-bromo-7-methoxy, 2-bromo-7-propoxy, 2-bromo-7-hexoxy, 2-nitro-7-propoxy, 2-nitro-7-hexoxy, and 2,7-di-bromo) dibenzofulvenes have been prepared from the corresponding fluorenes with fair to very good overall yields (35.7-66.7%) based on the Wittig chemistry. The new approach enjoyed much simpler experimental procedures and has the advantage of higher functional group tolerance. Preliminary results on their polymerization using solution free-radical approach are also presented.
