725724-83-4

Upstream product

• 75658-86-5 (1S,5R)-3-oxabicyclo[3.1.0]hexan-2-one 
• 917-54-4 methyllithium 
• 100-39-0 benzyl bromide 

Downstream Products

• 725724-84-5 (1S,2R)-2-[(benzyloxy)methyl]-1-isopropenylcyclopropane 
• 1027596-81-1 (R)-2-((1S,2R)-2-Benzyloxymethyl-cyclopropyl)-propionaldehyde 
• 725724-85-6 (2R)-2-{(1R,2R)-2-[(benzyloxy)methyl]cyclopropyl}propan-1-ol 
• 725724-88-9 (4S)-4-{(1R,2R)-2-[(benzyloxy)methyl]cyclopropyl}pentanal 
• 725724-86-7 ethyl (E),(4R)-4-{(1R,2R)-2-[(benzyloxy)methyl]cyclopropyl}pent-2-enoate 
• 725724-87-8 ethyl (4S)-4-{(1R,2R)-2-[(benzyloxy)methyl]cyclopropyl}pentanoate 
• 725724-89-0 (1S,3S,4S,7S)-7-{(1R,2R)-2-[(benzyloxy)methyl]cyclopropyl}-4-hydroxy-1,3-dimethyl-2-oxooctyl benzoate 

Relevant academic research and scientific papers

Total synthesis of zincophorin and its methyl ester

A total synthesis of the naturally occurring ionophore zincophorin has been realized. The route features an intramolecular oxymercuration of a cyclopropanemethanol and a Carroll-Claisen rearrangement for the respective elaboration of the C1-C12 and C13-C25 subunits, which have been assembled by using a highly diastereoselective titanium-mediated aldol condensation.