7259-85-0Relevant academic research and scientific papers
Unravelling Lawesson's reagent: The structure of monomeric (4-methoxyphenyl)phosphine disulfide
Mardyukov, Artur,Niedek, Dominik,Schreiner, Peter R.
supporting information, p. 2715 - 2718 (2018/03/21)
We describe the isolation as well as IR and UV/Vis spectroscopic characterization of (4-methoxyphenyl)phosphine disulfide in argon matrices at 10 K. The title compound proved to be highly photolabile; irradiation with UV light (λ = 334 nm) led to rearrang
Dithiaphosphagermetannes-1,3,2,4 et dithiaphosphadigermolannes-1,4,5,2,3
Barrau, J.,Amine, M. El,Rima, G.,Satge, J.
, p. 615 - 620 (2007/10/02)
The synthesis of the new germylated and phosphorylated heterocycles 2-anisyl-4,4-dimethyl-2-thio-1,3,2,4-dithiaphosphagermetane, (1), and 5-anisyl-2,2,3,3-tetramethyl-5-thio-1,4,5,2,3-dithiaphosphadigermolane, (2), are described.The decomposition of 1 with formation of (Me2GeS)3 and (AnPS2)n is observed at room temperature.At 200 deg C 2 undergoes thermal fragmentation leading to (Me2GeS)3 and (AnPS)n.These results are explained by two mechanisms of decomposition involving formation of transient species and or , respectively.Exchange reactions between 2 and various metal (MIVB) chlorides are described.With Me2SiCl2 the reaction leads to silathione , probably via transient dithiaphosphasiletane.
