72592-67-7Relevant academic research and scientific papers
Oxidative olefination of anilides with unactivated alkenes catalyzed by an (electron-deficient η5-cyclopentadienyl)rhodium(III) complex under ambient conditions
Takahama, Yuji,Shibata, Yu,Tanaka, Ken
, p. 9053 - 9056 (2015)
The oxidative olefination of sp2 C-H bonds of anilides with both activated and unactivated alkenes using an (electron-deficient η5-cyclopentadienyl)rhodium(III) complex is reported. In contrast to reactions using this electron-defici
Rhodium-Catalyzed β-Selective Oxidative Heck-Type Coupling of Vinyl Acetate via C-H Activation
Zhang, Hui-Jun,Lin, Weidong,Su, Feng,Wen, Ting-Bin
supporting information, p. 6356 - 6359 (2016/12/23)
An efficient Rh(III)-catalyzed direct ortho-C-H olefination of acetanilides with vinyl acetate was developed. This protocol provides a straightforward pathway to a series of (E)-2-acetamidostyryl acetates, giving access to indole derivatives following a simple hydrolysis/cyclization process.
Ortho Vinylation of Aromatic Amides via Cyclopalladation Complexes
Horino, Hiroshi,Inoue, Naoto
, p. 4416 - 4422 (2007/10/02)
The reaction of acetanilide and meta- and para-substituted acetanilides with palladium acetate has given new ortho-palladated complexes 2a-j, which reacted with carbon monoxide, ethylene, or methyl vinyl ketone to produce the corresponding N-acylanthranilic esters 4a-m, 2-acetaminostyrenes 9k-p, and 4-aryl-3-buten-2-one derivatives 9a-j, respectively.Reactions of 2a with substituted olefins proceeded readily to give the 2-olefins 8a-h.Ortho-substituted acetanilides and N-methylacetanilide did not undergo complex formation with palladium acetate.
