726138-55-2

Upstream product

• 1087244-24-3 Ru(2,6-(CH₂P-tBu₂)2C₆H₃)(CO)Cl 
• 20732-26-7 lithium anilide 
• 75-05-8 acetonitrile 
• 594-09-2 trimethylphosphane 
• 726138-54-1 (2,6-(CH₂P(t)Bu₂)2C₆H₃)Ru(CO)(trimethylphosphine)(NHPh) 
• 726138-56-3 (2,6-(CH₂P(t)Bu₂)2C₆H₃)Ru(CO)(N(H)C(C₆F₅)NPh) 

Downstream Products

• 851706-08-6 (2,6-(CH₂P(t)Bu₂)2C₆H₃)Ru(CO)(N(Ph)C(Ph)NH) 
• 726138-56-3 (2,6-(CH₂P(t)Bu₂)2C₆H₃)Ru(CO)(N(H)C(C₆F₅)NPh) 
• 851706-09-7 (2,6-(CH₂P(t)Bu₂)2C₆H₃)Ru(CO)(N(Ph)C(p-FC₆H₄)NH) 
• 851706-10-0 (2,6-(CH₂P(t)Bu₂)2C₆H₃)Ru(CO)(N(Ph)C(p-MeC₆H₄)NH) 

Relevant academic research and scientific papers

Reactions of (PCP)Ru(CO)NHPh(PMe3) (PCP = 2,6-(CH 2PtBu2)2C6H3) with substrates that possess polar bonds

The Ru(II) amido complex (PCP)Ru(CO)(PMe3)(NHPh) (1) (PCP = 2,6-(CH2PtBU2)2C6H 3) reacts with compounds that possess polar C=N, C≡N, or C=O bonds (e.g., nitriles, carbodiimides,

Ruthenium(II) anilido complex containing a bisphosphine pincer ligand: Reversible formation of amidinate ligands via intramolecular C-N bond formation

The reaction of the octahedral anilido complex (PCP)Ru(CO)(NHPh)(PMe 3) with acetonitrile produces the amidinate complex (PCP)Ru(CO){N(H)C(Me)N-(Ph)}. Mechanistic studies indicate that the reaction proceeds through coordination of the nitrile to the Ru(II) metal center, followed by intramolecular nucleophilic addition of the amido ligand.