726159-14-4Relevant academic research and scientific papers
DENITROHYDROGENATION OF ALIPHATIC NITRO COMPOUNDS AND A NEW USE OF ALIPHATIC NITRO COMPOUNDS AS RADICAL PRECURSORS
Ono, Noboru,Miyake, Hideyoshi,Kamimura, Akio,Hamamoto, Isami,Tamura, Rui,Kaji, Aritsune
, p. 4013 - 4024 (1985)
Aliphatic nitro groups are replaced by hydrogen on treatment with tributyltin hydride which proceeds via free radical chain processes.As the nitro group is selectively denitrated and other reducible groups are not affected with tributyltin hydride, this reaction can be used as a method for removing the nitro group from polyfunctional compounds.The radical intermediates generated via denitration can be also used for the carbon-carbon bond forming reactions.
Unprecedented in situ oxidative ring cleavage of isoxazolidines: Diastereoselective transformation of nitronic acids and derivatives into 3-hydroxymethyl 4-nitro tetrahydrofurans and pyrrolidines
Roger, Pierre-Yves,Durand, Anne-Catherine,Rodriguez, Jean,Dulcere, Jean-Pierre
, p. 2027 - 2029 (2007/10/03)
Equation presented. Nitronic acids undergo an intramolecular 1,3-dipolar cycloaddition to unactivated double bonds, and the resulting isoxazolidines spontaneously evolve by an unprecedented in situ oxidative ring cleavage. The extension of this transforma
