72708-78-2Relevant academic research and scientific papers
Addition of 4-Phenyltriazolinedione to Carbonyl Compounds: The Formation of α-Urazolylcarbonyl Compounds
Wilson, R. Marshall,Hengge, Alvan C.,Ataei, Ali,Chantarasiri, Nuanphun
, p. 193 - 197 (2007/10/02)
N-Phenyltriazolinedione (PTAD) adds to a variety of carbonyl compounds to form α-urazolylcarbonyl compounds.With highly enolized carbonyl systems, this type of substitution reaction can occur rapidly even in the absence of a catalyst.However, with simple
Mechanistic Studies of the Reaction of 4-Substituted 1,2,4-Triazoline-3,5-diones with β-Dicarbonyl Compounds
Williams, Grady A.,Butler, George B.
, p. 1232 - 1239 (2007/10/02)
4-Substituted 1,2,4-triazoline-3,5-diones were found to add to the α position of β-diketones and β-diketo esters, yielding both 1:1 and 2:1 adducts.The 1:1 adducts showed a dramatic stabilization of the enolic tautomer when compared to the original β-dica
