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Synthesis and Crystal Structures of New Palladium(II)-Gallium(III) Complexes with Bridging Halogenide Ligands
Gorlov, Mikhail,Fischer, Andreas,Kloo, Lars
, p. 324 - 326 (2004)
The reaction of palladium(II) bromide or palladium(II) iodide with the respective gallium(III) halogenide in the presence of aromatic solvents leads to the formation of palladium(II) tetrabromo- and tetraiodogallate. The compounds are isostructural {monoclinic, C2/m, Pd[GaBr4] 2: a=1267(2), b=808(1), c= 722(1) pm, β=94.5(1)°; Pd[GaI4]2: a=1363(1), b=849.9(4), c= 756.6(7) pm, β=95.38(3)°}. The structures contain mononuclear complexes Pd[GaX 4]2, where X - Br- (1), I- (2). The crystal structures of 1 and 2 were determined by single-crystal X-ray diffraction. Crystals of both compounds turned out to be similarly twinned.
