728023-31-2Relevant academic research and scientific papers
Unusual reaction of β-hydroxy α-diazo carbonyl compounds with TsNHN=CHCOCl/Et3N
Shi, Weifeng,Zhang, Bo,Liu, Binge,Xu, Feng,Xiao, Fengping,Zhang, Jian,Zhang, Shiwei,Wang, Jianbo
, p. 4563 - 4566 (2004)
The reaction of β-hydroxy α-diazo carbonyl compounds with TsNHN=CHCOCl/Et3N gave β-(p-tolylsulfonyl) α,β- unsaturated carbonyl compounds or β-(p-tolylsulfonyl) α-diazo esters. The reaction mechanism is discussed.
Stereoselective intramolecular 1,3 C-H insertion in Rh(II) carbene reactions
Shi, Weifeng,Zhang, Bo,Zhang, Jian,Liu, Binge,Zhang, Shiwei,Wang, Jianbo
, p. 3103 - 3106 (2007/10/03)
(Chemical Equation Presented) 1,3 C-H insertion has been found to be a predominant reaction pathway in the Rh(II)-mediated reaction of β-tosyl α-diazo carbonyl compounds.
