72842-33-2Relevant articles and documents
One-step Synthesis of Functionalized Dioxaspirodecanes from β-Phenylsulfonyl Dihydrofurans and γ-Lactones
Carretero, Juan C.,Diaz, Nuria,Rojo, Javier
, p. 6917 - 6920 (2007/10/02)
A one-step synthesis of differently substituted 1,6-dioxaspirodecanes from readily available starting materials is described.The process is based on the condensation of the α-anion derived from β-phenylsulfonyl dihydrofurans with γ-lactones.The spirocyclization occurs with high stereoselectivity at C-4, C-5 and C-9, but not at C-2.