72867-87-9

Upstream product

• 72867-85-7 3-Methyl-4-(7-methyl-12-(trimethylsilyl)-trans,trans-3,7-dodecadien-11-ynyl)-2-cyclohexenone Ethylene Thioketal 
• 72867-77-7 2-Methyl-7-(trimethylsilyl)-1-hepten-6-yn-3-ol 
• 72867-79-9 4-Methyl-9-(trimethylsilyl)-trans-4-nonen-8-ynol 
• 68707-00-6 5-(Trimethylsilyl)-4-pentynal Diethyl Acetal 
• 72867-80-2 4-Methyl-9-(trimethylsilyl)-trans-4-nonen-8-ynal 
• 72867-78-8 Methyl 4-Methyl-9-(trimethylsilyl)-trans-4-nonen-8-ynoate 
• 68654-85-3 5-(trimethylsilyl)pent-4-ynal 
• 68654-84-2 4-pentynyl diethyl acetal 

Downstream Products

• 68654-91-1 3-Methyl-4-(7-methyl-12-(trimethylsilyl)-trans,trans-3,7-dodecadien-11-ynyl)-2-cyclohexenol 

Relevant academic research and scientific papers

Biomimetic Polyene Cyclizations. Participation of the (Trimethylsilyl)acetylenic Group and the Total Synthesis of the D-Homosteroid System.

The aim of this study was to examine the (trimethylsilyl)acetylenic group as a terminator in biomimetic polyene cyclizations.Two cyclization substrates, 2 and 4, containing this group were synthesized by the sequence outlined in Schemes I and II.Cyclizati