Biomimetic Polyene Cyclizations. Participation of the (Trimethylsilyl)acetylenic Group and the Total Synthesis of the D-Homosteroid System.

DOI: 10.1021/jo01295a019

Source and publish data:

Journal of Organic Chemistry p. 1254 - 1259 (1980)

Update date:2022-08-02

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Authors:

Johnson, William S.

Yarnell, Thomas M.

Myers, Robert F.

Morton, Douglas R.

Boots, Sharon G.

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Article abstract of DOI:10.1021/jo01295a019

The aim of this study was to examine the (trimethylsilyl)acetylenic group as a terminator in biomimetic polyene cyclizations.Two cyclization substrates, 2 and 4, containing this group were synthesized by the sequence outlined in Schemes I and II.Cyclizati

Full text of DOI:10.1021/jo01295a019

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