7287-36-7 Usage
Uses
Different sources of media describe the Uses of 7287-36-7 differently. You can refer to the following data:
1. MONALIDE is used to destroyweeds of crops such as carrots, celery, and parsley.
2. Preemergence and postemergence control of broad-leaved weeds in parsley, carrots,
dill and celery.
Environmental Fate
Biological. In the presence of suspended natural populations from unpolluted aquatic
systems, the second-order microbial transformation rate constant determined in the laboratory
was reported to be 6 ′ 10–13 L/organisms-hour (Steen, 1991).Soil. Probably degrades via ring hydroxylation and subsequent ring cleavage. Persistence
in soil is limited to approximate 6–8 weeks (Hartley and Kidd, 1987). Under
laboratory conditions, the half-lives in soil were 30, 48 and 59 days at pH 4.85,
Check Digit Verification of cas no
The CAS Registry Mumber 7287-36-7 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,2,8 and 7 respectively; the second part has 2 digits, 3 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 7287-36:
(6*7)+(5*2)+(4*8)+(3*7)+(2*3)+(1*6)=117
117 % 10 = 7
So 7287-36-7 is a valid CAS Registry Number.
InChI:InChI=1/C13H18ClNO/c1-4-9-13(2,3)12(16)15-11-7-5-10(14)6-8-11/h5-8H,4,9H2,1-3H3,(H,15,16)
7287-36-7Relevant articles and documents
Palladium-Catalyzed Markovnikov Hydroaminocarbonylation of 1,1-Disubstituted and 1,1,2-Trisubstituted Alkenes for Formation of Amides with Quaternary Carbon
Yang, Hui-Yi,Yao, Ya-Hong,Chen, Ming,Ren, Zhi-Hui,Guan, Zheng-Hui
supporting information, p. 7298 - 7305 (2021/05/26)
Hydroaminocarbonylation of alkenes is one of the most promising yet challenging methods for the synthesis of amides. Herein, we reported the development of a novel and effective Pd-catalyzed Markovnikov hydroaminocarbonylation of 1,1-disubstituted or 1,1,2-trisubstituted alkenes with aniline hydrochloride salts to afford amides bearing an α quaternary carbon. The reaction makes use of readily available starting materials, tolerates a wide range of functional groups, and provides a facile and straightforward approach to a diverse array of amides bearing an α quaternary carbon. Mechanistic investigations suggested that the reaction proceeded through a palladium hydride pathway. The hydropalladation and CO insertion are reversible, and the aminolysis is probably the rate-limiting step.
