728920-93-2Relevant academic research and scientific papers
Catalytic isomerization of cyanoolefins involved in the adiponitrile process. C-CN bond cleavage and structure of the nickel π-allvl cyanide complex Ni(η3-1-Me-C3H4)(CN)(dppb)
Chaumonnot, Alexandra,Lamy, Franck,Sabo-Etienne, Sylviane,Donnadieu, Bruno,Chaudret, Bruno,Barthelat, Jean-Claude,Galland, Jean-Christophe
, p. 3363 - 3365 (2008/10/09)
Isomerization of 2-methyl-3-butenenitrile to 3-pentenenitrile is catalyzed by nickel π-allyl cyanide complexes. The mechanism is supported by in situ NMR monitoring and DFT studies.
