7290-25-7Relevant academic research and scientific papers
Enantioselective synthesis of dityrosine and isodityrosine via asymmetric phase-transfer catalysis
Lygo
, p. 1389 - 1392 (2007/10/03)
Application of N-anthracenylmethyl cinchonidinium chloride quaternary ammonium phase-transfer catalysts to the enantio- and diastereoselective synthesis of dityrosine and isodityrosine is reported. Under liquid-liquid phase-transfer conditions the key α-amino acid substituents are introduced with high enantioselectivity (≥95%e.e.).
Alkylations of chiral imidazolidinones derived from di- and triglycine and attempts at cyclisations to give cycloisodityrosines
Bezencon, Olivier,Seebach, Dieter
, p. 1259 - 1276 (2007/10/03)
Di- and triglycine derivatives (1-5) containing a 2-tert-butyl-1,3-imidazolidin-4-one moiety were prepared in rac. and enantiopure forms. By deprotonations with LiNR2 these imidazolidinones were converted to Li, Li2, and Li3/su
