729613-18-7Relevant academic research and scientific papers
Efficient synthesis of fluoroalkenes via diethylzinc-promoted wittig reaction
Zoute, Ludivine,Dutheuil, Guillaume,Quirion, Jean-Charles,Jubault, Philippe,Pannecoucke, Xavier
, p. 3409 - 3418 (2006)
The synthesis of α-fluoroacrylates and α-bromo-α- fluoroalkenes was achieved in very good yields using aldehydes and ketones, triphenylphosphine, diethylzinc as promoter, and ethyl dibromofluoroacetate or dibromofluoromethane, respectively. A change in th
Chromium-mediated fluoroalkenylation reactions of 1,1-dibromo-1- fluoroalkane and 1-bromo-1-fluoroalkene derivatives
Saito, Akio,Nakagawa, Muga,Taguchi, Takeo
, p. 1166 - 1173 (2007/10/03)
CrCl2- and NiCl2-mediated coupling reactions of E/Z mixture of 1-bromo-1-fluoroalkenes with aldehydes proceeded in a high stereoselectivity to give the corresponding (Z)-2-fluoroallylic alcohol derivatives. On the other hand, in the
A facile and mild method for the synthesis of terminal bromofluoroolefins via diethylzinc-promoted wittig reaction
Lei, Xinsheng,Dutheuil, Guillaume,Pannecoucke, Xavier,Quirion, Jean-Charles
, p. 2101 - 2104 (2007/10/03)
Synthesis of 1-bromo-1-fluoroolefins was achieved in good yields via a Wittig reaction promoted by diethylzinc, even with nonactivated aldehydes and ketones as starting materials.
