72997-91-2Relevant academic research and scientific papers
Aminopyridinium iodide as a NH transferring agent for the synthesis of 2-aroyl-3-aryl aziridines
Samimi, Heshmat A.,Momeni, Ahmad R.
, p. 2221 - 2225 (2015/10/19)
A new approach for the synthesis of N-H ketoaziridines is described. 1-aminopyridinium iodide as a NH transferring agent provides a straightforward access to the 2-aroyl-3-arylaziridines from the corresponding 1,3-diarylprop-2-en-1-one. A possible general mechanism involving the N-N ylide is proposed.
Direct NH-aziridination of α,β-unsaturated ketones
Xu, Jiaxi,Jiao, Peng
, p. 1491 - 1493 (2007/10/03)
1-Aryl-α,β-unsaturated ketones were directly aziridinated, N-unsubstituted, in a one-pot reaction with satisfactory yields by N,N′-diamino-1,4-diazoniabicyclo[2.2.2]octane dinitrate, a nitrogen-nitrogen ylide precursor, in the presence of sodium hydride.
