73013-91-9Relevant academic research and scientific papers
Kinetics of Reactions of Amines with α-Nitro-β-substituted-stilbenes in 50percent Me2SO-50percent Water. Search for the Intermediate in Nucleophilic Vinylic Substitution Reactions
Bernasconi, Claude F.,Fassberg, Julianne,Killion, Robert B.,Rappoport, Zvi
, p. 4568 - 4575 (2007/10/02)
The kinetics of the reaction of Ph(OMe)C=CPh(NO2) with piperidine, morpholine, pyrrolidine, and n-butylamine, and of the reactions of piperidine with Ph(Cl)C=CPh(NO2), Ph(I)C=CPh(NO2), and Ph(SEt)C=CPh(NO2) were measured in 50percent Me2SO-50percent water
Nucleophile and Nucleofuge Effects, Catalysis, and Stereochemistry in Vinylic Substitution of Electrophilic Nitro Olefins
Rappoport, Zvi,Topol, Alain
, p. 5967 - 5977 (2007/10/02)
The substitution of (E)- and (Z)-β-iodo-α-nitrostilbenes (E-3-I and Z-3-I) and of the (E)-β-chloro (E-3-Cl) and of (E)-β-nitro (E-3-NO2) analogues with several nucleophiles were studied in MeCN and EtOH.Amine catalysis in the substitution with morpholine
