73013-87-3

Upstream product

• 501-65-5 diphenyl acetylene 
• 64-19-7 acetic acid 

Downstream Products

• 73013-91-9 4-((E)-2-Nitro-1,2-diphenyl-vinyl)-morpholine 
• 128534-71-4 cis-α-Nitro-β-(N-morpholino)stilbene 
• 73013-88-4 C₁₅H₁₀N₂O₂S 
• 73013-89-5 1-Methyl-4-((E)-2-nitro-1,2-diphenyl-vinylsulfanyl)-benzene 
• 5585-14-8 3,4-diphenyl-furazan 2-oxide 
• 73013-90-8 1-((E)-2-Nitro-1,2-diphenyl-vinyl)-piperidine 
• 55902-52-8 cis-α-nitro-β-piperidinostilbene 

Relevant academic research and scientific papers

Method for synthesizing beta-iodo-nitroolefin compound

The invention provides a method for synthesizing a beta-iodo-nitroolefin compound as shown in a formula (III). The method comprises: mixing substituted alkyne shown in a formula (I), an iodine source and tert-butyl nitrite shown in a formula (II) in a sol

Reactions of alkynes with iodine and potassium iodide in acetic acid in the presence of nitrates. Simple synthesis of 1-iodo-2-nitroalkenes

Terminal and internal alkynes react with I2 or KI and nitrates in acetic acid under mild conditions to give the corresponding 1-iodo-2-nitroalkenes as the major products. The effect of the reactant nature and reaction conditions on the yield of products was studied. Oxygen was found to play an important role in the formation of the target products. A possible mechanism of the reaction includes a series of redox transformations of I2 or I- and NO-3 to form INO2 which then adds to alkynes by a radical path. In reactions with potassium iodide, oxygen acts as an additional oxidant which converts NO into active nitrogen dioxide.

A facile synthesis of α-iodo-β-nitroalkenes from alkynes using I2/NO3- or KI/NO3-

A convenient method with I2/NO3- or KI/NO3- has been developed for the synthesis of α-iodo-β-nitroalkenes from alkynes.