73045-60-0

Upstream product

• 67381-27-5 methyl 3-O-allyl-α-D-mannopyranoside 
• 108-24-7 acetic anhydride 
• 73045-58-6 methyl 2,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 617-04-9 (2R,3S,4S,5S,6S)-2-(hydroxymethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triol 
• 73045-61-1 methyl 3-O-allyl-2,4,6-tri-O-benzyl-α-D-mannopyranoside 

Downstream Products

• 745822-36-0 3-O-acetyl-2,4,6-tri-O-benzyl-1-deoxy-1-(prop-2-enyl)-α-D-mannopyranose 
• 75961-99-8 1,3-anhydro-2,4,6-tri-O-benzyl-β-D-mannopyranose 
• 84553-75-3 3-O-acetyl-2,4,6-tri-O-benzyl-α-D-mannopyranosyl chloride 

Relevant academic research and scientific papers

Ceric ammonium nitrate/acetic anhydride: A tunable system for the O-acetylation and mononitration of diversely protected carbohydrates

Esterification of a wide range of partially protected carbohydrate derivatives was achieved using acetic anhydride and a catalytic amount of ceric ammonium nitrate (CAN). Compatibility with the commonly used protecting groups was demonstrated, with the es

Preparation of an advanced intermediate for the synthesis of stable analogues of guanofosfocin

The synthesis of C-mannosyl-guanosine 23, an advanced intermediate for the preparation of stable analogues of guanofosfocin, is described. This convergent approach features an improved Traube-type synthesis of a 8-substituted guanine, followed by ribosylation. NMR Studies show that the C-mannopyranosyl moiety of 23 adopts a distorted 1C4 conformation while the nucleoside is predominantly syn-oriented.