73045-61-1

Upstream product

• 617-04-9 (2R,3S,4S,5S,6S)-2-(hydroxymethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triol 
• 73415-94-8 methyl 2,4,6-Tri-O-acetyl-3-O-allyl-α-D-mannopyranoside 
• 100-44-7 benzyl chloride 

Downstream Products

• 75961-97-6 methyl 2,4,6-Tri-O-benzyl-3-O-propenyl-α-D-mannopyranoside 
• 84553-76-4 3-O-allyl-2,4,6-tri-O-benzyl-D-mannopyranoside 
• 106444-73-9 methyl 3-O-allyl-2,6-di-O-benzyl-α-D-mannopyranoside 
• 75961-98-7 2,4,6-Tri-O-benzyl-α-D-mannopyranosyl Chloride 
• 75961-99-8 1,3-Anhydro-2,4,6-tri-O-benzyl-α-D-mannopyranose 
• 84553-77-5 2,4,6-tri-O-benzyl-3-O-(1-propenyl)-D-mannopyranose 
• 37111-85-6 2,4,6-tri-O-benzyl-D-mannopyranose 
• 745822-36-0 3-O-acetyl-2,4,6-tri-O-benzyl-1-deoxy-1-(prop-2-enyl)-α-D-mannopyranose 
• 73045-60-0 methyl 3-O-acetate-2,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 73045-58-6 methyl 2,4,6-tri-O-benzyl-α-D-mannopyranoside 

Relevant academic research and scientific papers

Preparation of an advanced intermediate for the synthesis of stable analogues of guanofosfocin

The synthesis of C-mannosyl-guanosine 23, an advanced intermediate for the preparation of stable analogues of guanofosfocin, is described. This convergent approach features an improved Traube-type synthesis of a 8-substituted guanine, followed by ribosylation. NMR Studies show that the C-mannopyranosyl moiety of 23 adopts a distorted 1C4 conformation while the nucleoside is predominantly syn-oriented.

Synthesis of Substituted 2,6-Dioxabicycloheptanes. 1,3-Anhydro-2,4,6-tri-O-benzyl- and 1,3-Anhydro-2,4,6-tri-O-(p-bromobenzyl)-β-D-mannopyranose

The title compounds 1,3-anhydro-2,4,6-tri-O-benzyl- and 1,3-anhydro-2,4,6-tri-O-(p-brombenzyl)-β-D-mannopyranose were synthesized by a reaction sequence involving blocking the C-3 hydroxyl with an allyl group by first forming a dibutylstannylene complex b