73046-16-9Relevant articles and documents
Rational Synthesis of Metallo-Cations Toward Redox- A nd Alkaline-Stable Metallo-Polyelectrolytes
Zhu, Tianyu,Sha, Ye,Firouzjaie, Horie Adabi,Peng, Xiong,Cha, Yujin,Dissanayake, D. M. M. Mevan,Smith, Mark D.,Vannucci, Aaron K.,Mustain, William E.,Tang, Chuanbing
supporting information, p. 1083 - 1089 (2020/01/31)
Cations are crucial components in emerging functional polyelectrolytes for a myriad of applications. Rapid development in this area necessitates the exploration of new cations with advanced properties. Herein we describe a combination of computational and experimental design of cobaltocene metallo-cations that have distinct electronic and redox properties. One of the direct outcomes on the first synthesis of a complete set of cation derivatives is to discover highly stable cations, which are further integrated to construct metallo-polyelectrolytes as anion-exchange membranes in solid-state alkaline fuel cells. The device performance of these polyelectrolytes under highly basic and oxidative environments is competitive with many organo-polyelectrolytes.
Improved Preparation of Polyisopropyl- and -tert-butylcyclopentadienes
Dehmlow, Eckehard V.,Bollmann, Christof
, p. 457 - 460 (2007/10/02)
Phase transfer catalytic isopropylation or tert-butylation of cyclopentadiene yields 1-6 in efficient one-pot procedures.Powdered potassium hydroxide or solid sodium hydride are the prefered bases, Aliquat 336 or dibenzo-18-crown-6 are the PT catalysts. +"--"+ Phase Transfer Catalysis, Potassium Hydroxide, Sodium Hydride
Di-tert-butylcyclopentadiene and tri-tert-butylcyclopentadiene
Venier, Clifford G.,Casserly, Edward W.
, p. 2808 - 2809 (2007/10/02)
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