731016-44-7

Usage

Uses

Used in Organic Synthesis:
3-Bromo-9-p-tolyl-9H-carbazole is used as a key intermediate in organic synthesis for the production of various organic compounds. Its unique structure allows for further functionalization and modification, making it a valuable building block in the synthesis of complex organic molecules.
Used in Materials Science:
In the field of materials science, 3-Bromo-9-p-tolyl-9H-carbazole is utilized for the development of advanced materials with specific properties. Its presence in these materials can enhance their performance, stability, and other characteristics, making it a useful component in the creation of novel materials.
Used in Organic Semiconductors:
3-Bromo-9-p-tolyl-9H-carbazole is employed as a component in the development of organic semiconductors. Its electronic properties and structural features make it suitable for use in the fabrication of organic electronic devices, such as organic field-effect transistors (OFETs) and organic solar cells.
Used in Electronic Devices:
3-Bromo-9-p-tolyl-9H-carbazole is used in the production of electronic devices, particularly in the development of organic light-emitting diodes (OLEDs). Its incorporation into these devices can improve their efficiency, brightness, and overall performance, making it a valuable component in the design and fabrication of OLEDs.
Used in Optoelectronic Applications:
3-Bromo-9-p-tolyl-9H-carbazole is utilized in optoelectronic applications due to its light-emitting and light-absorbing properties. Its use in these applications can lead to the development of advanced optoelectronic devices with improved performance and functionality.
Used in Pharmaceutical and Biological Research:
Although its specific biological effects have not been fully elucidated, 3-Bromo-9-p-tolyl-9H-carbazole has been studied for its potential pharmacological and biological activities. Its unique structure and properties make it a promising candidate for further research in drug discovery and development, as well as in the study of biological processes and mechanisms.

Upstream product

• 86-74-8 9H-carbazole 
• 624-31-7 4-tolyl iodide 
• 1592-95-6 3-bromo-9H-carbazole 
• 539-44-6 N-4-methylphenylhydrazine 
• 106-38-7 para-bromotoluene 
• 19264-73-4 9-(4-methylphenyl)-9H-carbazole 

Downstream Products

• 1260378-67-3 C₉₀H₁₀₃NO 
• 731016-45-8 N-p-tolyl-3-carbazoleboronic acid 
• 1385028-97-6 C₄₃H₃₁N₃ 
• 1345614-94-9 4,6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9-(p-tolyl)-1,2,3,4,4a,9a-hexahydrocarbazole 

Relevant academic research and scientific papers

9-(p-Tolyl)-2,3,4,4a,9,9a-hexahydro-1H-carbazole—A new donor building-block in the design of sensitizers for dye-sensitized solar cells

The novel donor building-block - 9-(p-tolyl)-2,3,4,4a,9,9a-hexahydro-1H-carbazole was designed and employed in the synthesis of dye-sensitized solar cell (DSSCs). An effective, high-yielding synthesis of 4,6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9-(p-tolyl)-1,2,3,4,4a,9a-hexahydrocarbazole from 1,2,3,4,4a,9a-hexahydrocarbazole was realized. Three new metal-free organic sensitizers, containing the new donor building block were prepared by a stepwise approach from 4,7-dibromobenzo[c][1,2,5]chacogenadiazoles. A 2,1,3-Benzothiadiazole dye containing hexahydrocarbazole donor, thiophene as π-spacer and cyanoacrylate as anchoring electron acceptor showed photovoltaic properties higher than the well-known WS-2 sensitizer with PCE = 5.86 %. Although benzoxa- and –selenadiazole dyes have a bathochromic shift (24?30 nm) in the UV–vis spectra, and smaller energy gap Eg (about 0.1 eV), they have lower photovoltaic parameters, including PCE of 1.5–2.3 %. Introducing a new donor 9-(p-tolyl)-2,3,4,4a,9,9a-hexahydro-1H-carbazole into the construction of the DSSCs has broadened possibilities for the optimization of their photovoltaic properties.

Method for synthesizing N-aryl carbazole compound by catalyzing reaction of carbazole with aryl hydrazine by using transition metal

The invention relates to a method for synthesizing an N-aryl carbazole compound by catalyzing reaction of carbazole with aryl hydrazine through transition metal. According to the method, a transitionmetal salt is used as a catalyst, a carbazole compound and an aryl hydrazine compound are used as reaction substrates, the reaction substrates and an alkali compound are added into a solvent for a reaction for a certain period of time to obtain a reaction solution, and the reaction solution is separated and purified to obtain the N-aryl carbazole compound. According to the method, low-boiling-point acetonitrile is used as a reaction solvent, so post-reaction treatment is easy to carry out; oxygen in the air serves as an oxidizing agent, so reaction conditions are environmentally friendly and safe, cost is low, and excessive oxidation is avoided; an aryl hydrazine compound is used as an arylation reagent, and reaction byproducts only comprise water and nitrogen, so the method is environment-friendly and pollution-free; the transition metal salt is used as the catalyst, the activity of the transition metal salt is high, the use of equivalent noble metals is avoided, and synthesis cost isreduced; and generally speaking, the synthesis method is friendly to environment, simple in process, good in reaction selectivity and high in yield, and has a relatively strong industrial applicationprospect.

Synthesis, photoluminescence properties of novel cationic Ir(III) complexes with phenanthroimidazole derivative as the ancillary ligand

Two novel cationic Ir(III) complexes, [(nbt)2Ir(L)](PF6) and [(CF3-bt)2Ir(L)](PF6), where nbt = 2-(1-naphthyl)benzothiazole; CF3-bt = 2-phenyl-6-(trifluoromethyl)-benzothiazole and L = 1-(4

Investigation of novel carbazole-functionalized coumarin derivatives as organic luminescent materials

Four new carbazole-based coumarin derivatives comprising a carbazole core and one or two coumarin chromophores, 7-(diethylamino)-3-(4-(9-(p-tolyl)-9H-carbazol-3-yl)phenyl)coumarin (Cz-Ph-C) and 3,3'-((9-(p-tolyl)-9H-carbazole-3,6-diyl)bis(4,4′-phenyl))bis

Bipolar hosts for light emitting devices

Some embodiments provide a compound represented by Formula 1: wherein R1, R2, R3, R4, R5, R6, R7 and R8 are independently H, C1-C3 alkyl, or C1-3 perfluoroalkyl; HT is optionally substituted carbazoyl, optionally substituted phenylcarbazolyl, optionally substituted (phenylcarbazolyl)phenyl, optionally substituted phenylnaphthylamine, or optionally substituted diphenylamine; and ET optionally substituted benzimidazol-2-yl, optionally substituted benzothiazol-2-yl, optionally substituted benzoxazol-2-yl, optionally substituted 3,3′-bipyridin-5-yl, optionally substituted quinolin-8-yl, optionally substituted quinolin-5-yl, or optionally substituted quinoxalin-5-yl. Other embodiments provide an organic light-emitting diode device comprising a compound of Formula 1.

Copper/β-diketone-catalysed N-arylation of carbazoles

A copper-catalysed C-N bond-forming reaction of carbazoles with aryl iodides is described. Several commercially available ligands such as β-diketone and diamine, are tested in the N-arylation of carbazoles. The catalytic system generated in situ from an inexpensive copper salt, simple β-diketone and inorganic base efficiently N-arylated the carbazoles. A wide range of aryl iodides and carbazoles can be coupled to generate N-arylcarbazoles in the presence of various functional groups. However, the sterically hindered effect of aryl iodides is evident in this catalytic system. The selectivity of two iodine atoms on the aromatic ring of diiodobenzene is evaluated in the developed catalytic system. Results showed that the selectivity of diiodobenzene can be tuned by the reaction temperature.

Optimizing the photovoltaic performance of thiocyanate-free ruthenium photosensitizers by structural modification of C^N cyclometalating ligand in dye-sensitized solar cells

Five new thiocyanate-free ruthenium(II) complexes with different electron-donating functionalized cyclometalating ligands C^N were synthesized, characterized and applied as photosensitizers in dye-sensitized solar cells (DSSCs). Their photophysical, electrochemical, thermal and photovoltaic properties have been investigated and density functional theory (DFT) calculations have been carried out on these dyes. These dyes exhibit good thermal stability with the onset decomposition temperature at 5% weight-loss (Td) of around 330 °C. The DSSC device using the Ru(II) dye with the 9-tolylcarbazole chromophore exhibited the highest power conversion efficiency (η) up to 3.39%, with a short-circuit photocurrent density (Jsc) of 8.06 mA cm-2, an open-circuit photovoltage (Voc) of 0.62 V and a high fill factor (ff) of 0.68 under illumination of an AM 1.5 solar cell simulator.

Blue fluorescence from the ligand and yellow phosphorescence from the iridium complex: High-efficiency wet-processed white organic light-emitting device

We synthesized four carbazole modified blue-emitting fluorescent ligands. These ligands coordinated with Ir3+ and four yellow-emitting phosphorescent complexes were obtained. A high-efficiency (current efficiency 20.6 cd/A) yellow electrophosphorescence device was wet-fabricated using the complex as a guest. The ligands can harvest and transfer energy to the complexes and a high efficiency (～18 cd/A) white-light emitting device (CIE 0.31, 0.39) was obtained using the ligand as the blue-fluorescence emitter and the complex as the yellow-phosphorescence emitter. Therefore, the ligand can be a coordinator, an emitter and partly, a host. This is beneficial to device efficiency and saving cost for large-scale manufacturing.