73111-80-5

Upstream product

• 3150-20-7 4-methoxyphenyl β-D-galactopyranoside 
• 503303-06-8 p-methoxyphenyl 6-O-tert-butyldiphenylsilyl-β-D-galactopyranoside 
• 503303-07-9 p-methoxyphenyl 3,4-O-isopropylidene-6-O-(tert-butyldiphenylsilyl)-β-D-galactopyranoside 
• 233589-82-7 p-methoxyphenyl 2-O-benzyl-3,4-O-isopropylidene-β-D-galactopyranoside 
• 100-39-0 benzyl bromide 
• 40269-01-0 methyl 3,4-O-isopropylidene-α-D-galactopyranoside 
• 71732-12-2 (3aR,4S,6S,7R,7aR)-4-(iodomethyl)-6-methoxy-2,2-dimethyltetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-7-ol 
• 305834-19-9 methyl 2-O-benzyl-6-deoxy-6-iodo-3,4-O,O-methylethylidene-α-D-galacto-pyranoside 
• 233589-83-8 (3aR,4S,6S,7R,7aS)-7-Benzyloxy-4-iodomethyl-6-(4-methoxy-phenoxy)-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran 

Downstream Products

• 233589-97-4 (Z)-(S)-4-Benzyloxy-4-((4R,5S)-2,2-dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-but-2-enoic acid methyl ester 
• 233589-84-9 (E)-(S)-4-Benzyloxy-4-((4R,5S)-2,2-dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-but-2-enoic acid methyl ester 
• 1312197-89-9 (1S,2S,3S,3aR,9aS)-1,2-isopropylidenedioxy-3-benzyloxy-octahydrocyclopenta[c]pyrazol[1,2-a]pyrazolidin-7-one 
• 1312197-97-9 (1S,2S,3S,3aR,5R,9aS)-1,2-isopropylidenedioxy-3-benzyloxy-5-phenyl-octahydrocyclopenta[c]pyrazol[1,2-a]pyrazolidin-7-one 
• 1312197-96-8 (1S,2S,3S,3aR,5S,9aS)-1,2-isopropylidenedioxy-3-benzyloxy-5-phenyl-octahydrocyclopenta[c]pyrazol[1,2-a]pyrazolidin-7-one 
• 233589-87-2 N-{(S)-1-[(S)-Benzyloxy-((4S,5S)-2,2-dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-methyl]-allyl}-2,2,2-trichloro-acetamide 
• 233589-86-1 2,2,2-Trichloro-acetimidic acid (E)-(S)-4-benzyloxy-4-((4R,5S)-2,2-dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-but-2-enyl ester 
• 233589-88-3 {(S)-1-[(S)-Benzyloxy-((4S,5S)-2,2-dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-methyl]-allyl}-carbamic acid tert-butyl ester 
• 233589-89-4 ((3aS,4S,5S,7aS)-4-Benzyloxy-2,2-dimethyl-3a,4,5,7a-tetrahydro-benzo[1,3]dioxol-5-yl)-carbamic acid tert-butyl ester 
• 233589-93-0 (S)-2-[(S)-Benzyloxy-((4R,5S)-2,2-dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-methyl]-but-3-en-1-ol 
• 233589-94-1 (R)-2-[(S)-Benzyloxy-((4R,5S)-2,2-dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-methyl]-but-3-en-1-ol 
• 233589-85-0 (E)-(S)-4-Benzyloxy-4-((4R,5S)-2,2-dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-but-2-en-1-ol 
• 233589-98-5 (Z)-(S)-4-Benzyloxy-4-((4R,5S)-2,2-dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-but-2-en-1-ol 
• 195245-32-0 5-O-benzyl-1,2,6-trideoxy-6-iodo-3,4-O,O-methylethylidene-L-lyxo-hex-1-enitol 

Relevant academic research and scientific papers

Stereoselective and regioselective one-pot synthesis of polyhydroxy bicyclic diazenes and hydrazones from methyl 6-deoxy-6-iodo-hexosides

An efficient, stereoselective, and base-controlled procedure for the preparation of polyhydroxy bicyclic diazenes and polyhydroxy bicyclic hydrazones is described, starting from sugar-derived methyl 6-deoxy-6-iodo-hexosides. The one-pot synthesis involves

Stereoselective synthesis of polyoxygenated linear diaza-triquinanes via intramolecular 1,3-dipolar cycloaddition of sugar-derived hex-5-enals

An efficient and stereoselective synthesis of diaza-triquinanes, the skeleton structures of many natural products, has been accomplished by intramolecular 1,3-dipolar cycloaddition of azomethine imine generated from sugar-derived hex-5-enal and pyrazolidi

The cobalt-catalyzed oxygenative radical route from hexopyranosides to carbapentofuranoses

Cobalt-catalyzed radical cyclization/oxygenation of various 6-iodohex-1-enitols gave in one step the carbocyclic analogs of pentofuranoses. The reaction was run under very mild conditions and gave moderate to good yields of carbapentofuranoses within a few hours. All the possible 6-iodohex-1-enitol stereoisomers were prepared, and the influence of relative configurations and protecting groups was studied.

A versatile approach to the synthesis of highly functionalised carbocycles

A synthetic route towards conduramine and carbasugar derivatives based on the transformation (i.e. two-carbon Wittig olefination and ester reduction) of the Vasella rearrangement product derived from D-galactose followed by either a [3,3] Overman or a [2,3]-Wittig-Still sigmatropic rearrangement, and subsequent ring-closing metathesis, is presented.

A new synthesis of carbapentofuranoses from carbohydrates

Carbafuranosides were synthesized in one step from various O-protected 1,2,6-trideoxy-6-iodo-hex-1-enitols by cobalt catalyzed 5-exo radical-cyclization under molecular oxygen. Yields were fair to good with interesting selectivities.