73127-59-0

Basic information

• Product Name: 4-<2-(4-iodobutyl)-1,3-dioxalan-2-yl>-1-methylbutyl-2,4-dimethoxy-6-<(phenylthio) methyl> benzoate
• Synonyms: 4-<2-(4-iodobutyl)-1,3-dioxalan-2-yl>-1-methylbutyl-2,4-dimethoxy-6-<(phenylthio) methyl> benzoate
• CAS NO: 73127-59-0
• Molecular Weight: 628.569
• Mol File: 73127-59-0.mol

Chemical Properties

• CAS DataBase Reference: 4-<2-(4-iodobutyl)-1,3-dioxalan-2-yl>-1-methylbutyl-2,4-dimethoxy-6-<(phenylthio) methyl> benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-<2-(4-iodobutyl)-1,3-dioxalan-2-yl>-1-methylbutyl-2,4-dimethoxy-6-<(phenylthio) methyl> benzoate(73127-59-0)
• EPA Substance Registry System: 4-<2-(4-iodobutyl)-1,3-dioxalan-2-yl>-1-methylbutyl-2,4-dimethoxy-6-<(phenylthio) methyl> benzoate(73127-59-0)

Safety Data

• Hazardous Substances Data: 73127-59-0(Hazardous Substances Data)

Upstream product

• 3884-71-7 bromo-5-pentanone-2 
• 111741-88-9 5-(1',3'-dithian-2'-yl)-1-(2-tetrahydropyranyloxy)pentane 
• 70719-51-6 methyl 2,4-dimethoxy-6-<(phenylthio) methyl>-benzoate 
• 74726-77-5 2-iodo-3,5-bis(methoxy)benzenemethanol 
• 246871-23-8 1-Chloromethyl-2-iodo-3,5-dimethoxy-benzene 
• 74726-76-4 2-bromo-3,5-dimethoxybenzyl alcohol 
• 19491-18-0 methyl 2-bromo-3,5-dimethoxybenzoate 
• 2150-37-0 methyl 3,5-dimethoxybenzoate 
• 111649-51-5 4-<2-(4-tetrahydropyranyloxybutyl)-1,3-dithian-2-yl>-1-methylbutyl-2,4-dimethoxy-6-(phenylthiomethyl) benzoate 
• 111649-53-7 4-<2-(4-methanesulfonyloxybutyl)-1,3-dithian-2-yl>-1-methylbutyl-2,4-dimethoxy-6-<(phenylthio) methyl> benzoate 
• 111649-54-8 9-methanesulfonyloxy-1-methyl-5-oxo-nonyl-2,4-dimethoxy-6-<(phenylthio) methyl> benzoate 
• 111649-52-6 2,4-Dimethoxy-6-phenylsulfanylmethyl-benzoic acid 4-[2-(4-hydroxy-butyl)-[1,3]dithian-2-yl]-1-methyl-butyl ester 
• 111649-55-9 2,4-Dimethoxy-6-phenylsulfanylmethyl-benzoic acid 9-hydroxy-1-methyl-5-oxo-nonyl ester 
• 71787-00-3 2,4-Dimethoxy-6-phenylsulfanylmethyl-benzoyl chloride 

Relevant articles and documents

SYNTHESIS OF (+/-)-ZEARALENONE

The aliphatic portion of (+/-)-zearalenone has been synthesised by a new simple route starting from 2,3-dihydropyran and 2-acetyl-γ-butyrolactone by employing dithiane for C-C bond formation.The final condensation of this segment with the aromatic part and subsequent transformations led to (+/-)-zearalenone.

A GENERAL SYNTHETIC METHOD FOR ORSELLINIC ACID MOIETY OF MACROLIDES BY THE PALLADIUM-CATALYZED CARBONYLATION OF ARYL IODIDE AND ITS APPLICATION TO ZEARALENONE SYNTHESIS

Palladium-catalyzed carbonylation of 1-iodo-2-phenylthiomethyl-4,6-dimethoxybenzene (9) with 10-iodo-6,2'-dioxolane-2-decanol (10) afforded the corresponding ω-iodoalkyl ester of 2-phenylthiomethyl-4,6-dimethoxybenzoate (3) in 70percent yield, which