73172-59-5

Basic information

• Product Name: Methanone, [(2R,3S)-3-methyloxiranyl]phenyl-, rel-
• CAS NO: 73172-59-5
• Molecular Formula: C10H10O2
• Molecular Weight: 162.188
• Mol File: 73172-59-5.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Methanone, [(2R,3S)-3-methyloxiranyl]phenyl-, rel-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanone, [(2R,3S)-3-methyloxiranyl]phenyl-, rel-(73172-59-5)
• EPA Substance Registry System: Methanone, [(2R,3S)-3-methyloxiranyl]phenyl-, rel-(73172-59-5)

Safety Data

• Hazardous Substances Data: 73172-59-5(Hazardous Substances Data)

Upstream product

• 5623-21-2 α-allylbenzoin 
• 10133-06-9 methyl (+/-)-trans-(2,3)-epoxy butanoate 
• 591-51-5 phenyllithium 
• 121788-93-0 3-Chlor-1-phenyl-2-(trimethylsiloxy)-1-butanon 
• 75-07-0 acetaldehyde 
• 70-11-1 α-bromoacetophenone 
• 35660-91-4 (Z)-1-phenylbut-2-en-1-one 
• 35660-91-4 (E)-1-phenyl-2-buten-1-one 

Downstream Products

• 1210039-68-1 C₁₁H₁₂⁽²⁾H₂O₂ 
• 61752-45-2 Z-1-phenylpent-3-en-1-one 
• 74157-93-0 trans-1-phenyl-3-penten-1-one 
• 283166-69-8 3-hydroxy-2-(hydroxy-phenyl-methyl)-1-phenyl-butan-1-one 
• 34501-28-5 (+/-)-(RS)-((2SR,3SR)-3-methyloxiranyl)-phenylmethanol 
• 121359-05-5 trans-5-methyl-3-phenyl-2-isoxazolin-4-ol 

Relevant articles and documents

Benchtop-Stabssle Hypervalent Bromine(III) Compounds: Versatile Strategy and Platform for Air- And Moisture-Stable λ3-Bromanes

We present the first synthesis of air/moisture-stable λ3-bromanes (9and10) by using a cyclic 1,2-benzbromoxol-3-one (BBX) strategy. X-ray crystallography and NMR and IR spectroscopy ofN-triflylimino-λ3-bromane (12) revealed that the bromine(III) center is effectively stabilized by intramolecular R-Br-O hypervalent bonding. This strategy enables the synthesis of a variety of air-, moisture-, and benchtop-stable Br-hydroxy, -acetoxy, -alkynyl, -aryl, and bis[(trifluoromethyl)sulfonyl]methylide λ3-bromane derivatives.

Unprecedented direct oxygen atom transfer from hypervalent oxido-λ3-iodanes to α,β-unsaturated carbonyl compounds: Synthesis of α,β-epoxy carbonyl compounds

Tetra-n-butylammonium oxido-λ3-iodane, prepared from 1-hydroxy-1,2-benziodoxol-3(1H)-one by reaction with tetra-n-butylammonium fluoride, directly undergoes oxygen atom transfer to γ,β-unsaturated carbonyl compounds, yielding epoxides.

Baker's Yeast-mediated Transformations of α-Keto Epoxides

αβ-Epoxy ketones on treatment with baker's yeast yield different types of products depending on their substitution.Small groups such as H or Me attached at the epoxy end protect that end from attack.Thus,1-acyl epoxides with H, methyl or propyl as the 2-e