731785-49-2

Upstream product

• 624-92-0 Dimethyldisulphide 
• 731785-56-1 2-(N,N-diethyl-1-carbamoyloxyphenyl-2-)-1,3-dioxane 
• 88-10-8 N,N-diethylcarbamyl chloride 

Downstream Products

• 731785-63-0 N,N-diethyl-2-(2-hydroxy-3-methyl-phenylsulfanyl)-acetamide 
• 731785-55-0 N,N-diethyl-2-methylsulfanyl-6-methylcarbamoyloxybenzene 
• 25674-55-9 2-methyl-6-(methylsulfenyl)phenol 
• 731785-58-3 2-(3-[1,3]dioxan-2-yl-2-hydroxy-phenylsulfanyl)-N,N-diethyl-acetamide 
• 731785-57-2 N,N-diethyl-6-formyl-2-methylsulfanylcarbamoyloxybenzene 

Relevant academic research and scientific papers

Application of directed metalation in synthesis. Part 6: A novel anionic rearrangement under directed metalation conditions leading to heteroannulation

A short and efficient synthesis of condensed 1,4-oxathiin-2-ones from easily available phenols is described. The key step in this synthesis is a hitherto unreported anionic rearrangement under directed metalation conditions. The rearrangement occurs after