73183-22-9

Basic information

• Product Name: 4-(1-Cyano-2,2-dimethyl-4-oxo-1-trimethylsilanyloxy-pentyl)-benzonitrile
• CAS NO: 73183-22-9
• Molecular Weight: 328.486
• Mol File: 73183-22-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-(1-Cyano-2,2-dimethyl-4-oxo-1-trimethylsilanyloxy-pentyl)-benzonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(1-Cyano-2,2-dimethyl-4-oxo-1-trimethylsilanyloxy-pentyl)-benzonitrile(73183-22-9)
• EPA Substance Registry System: 4-(1-Cyano-2,2-dimethyl-4-oxo-1-trimethylsilanyloxy-pentyl)-benzonitrile(73183-22-9)

Safety Data

• Hazardous Substances Data: 73183-22-9(Hazardous Substances Data)

Upstream product

• 105-07-7 4-cyanobenzaldehyde 
• 141-79-7 4-methyl-pent-3-en-2-one 
• 73183-24-1 2-(4-cyanophenyl)-2-(trimethylsilyloxy)acetonitrile 

Downstream Products

• 73183-27-4 4-(2,2-Dimethyl-1,4-dioxopentyl)benzonitril 

Relevant articles and documents

Trimethylsilyl Cyanide - A Reagent for Umpolung, IV: Substituent Effectsin the Acylating Nucleophile for Directing 1,2-/1,4-Addition to α,β-Unsaturated Ketones

Mesityl oxide (6) is attacked by nucleophilic anions 5a-f in DME at the C-1 and/or C-3 position.Depending on the p-substituent in 5 the whole scale from 100percent 1,2-adduct 7 (with 5a, X = N(CH3)2) to 100percent 1,4-adduct 9 (with 5f, X = CN) is covered