73197-73-6

Basic information

• Product Name: chloro(8-quinolyl)bis(triphenylphosphine)nickel(II)
• CAS NO: 73197-73-6
• Molecular Weight: 746.878
• Mol File: 73197-73-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: chloro(8-quinolyl)bis(triphenylphosphine)nickel(II)(CAS DataBase Reference)
• NIST Chemistry Reference: chloro(8-quinolyl)bis(triphenylphosphine)nickel(II)(73197-73-6)
• EPA Substance Registry System: chloro(8-quinolyl)bis(triphenylphosphine)nickel(II)(73197-73-6)

Safety Data

• Hazardous Substances Data: 73197-73-6(Hazardous Substances Data)

Upstream product

• 15133-82-1 tetrakis(triphenylphosphine)nickel⁽⁰⁾ 
• 611-33-6 8-chloroquinoline 

Relevant articles and documents

Organonickel(II) Complexes Containing Carbon-bonded Heterocycles as a Ligand

Oxidative addition reactions of 2- and 3-chloropyridines and of 2-chloropyrazine to tetrakis(triphenylphosphine)nickel(0) occurred in toluene at ambient temperature to afford dinuclear nickel(II) complexes containing carbon-bonded heterocycles as a ligand.They are quite stable and the bridging chloride was readily substituted by other halides and pseudohalides preserving the dinuclear structure. 8-Chloroquinoline yielded a mononuclear complex as an exception.These novel organonickel(II) complexes were characterized by analytical and molecular weight data together with IR, 1H NMR, and 13C NMR spectra.Di-μ-chloro-bis(2-pyridyl)bis(triphenylphosphine)dinickel(II) was found to be an excellent catalyst for selective cross coupling of 2-chloropyridine with methylmagnesium bromide.