73209-88-8

Upstream product

• 122174-81-6 1,6-di-O-benzoyl-2,4:3,5-di-O-methylene-D-glucitol 
• 50-00-0 formaldehyd 
• 488-45-9 L-iditol 
• 13443-46-4 L-iditol hexaacetate 

Downstream Products

• 5349-04-2 O¹,O⁶-diacetyl-O²,O⁴;O³,O⁵-dimethanediyl-D-glucitol 
• 7465-84-1 O²,O⁴;O³,O⁵-dimethanediyl-O¹,O⁶-bis-(toluene-4-sulfonyl)-D-glucitol 
• 4539-77-9 2,4:3,5-Di-O-methylen-D-glucarsaeure-dimethylester 
• 5349-04-2 O¹,O⁶-diacetyl-O²,O⁴;O³,O⁵-dimethanediyl-D-mannitol 
• 7465-84-1 4,8-di-(tosyloxymethyl)-1,3,5,7-cis-tetraoxadecalin 
• 73186-07-9 2,4:3,5-dimethylene-D-mannitol 1-trans-cinnamate 6-(β-2-trans-thienylacrylate) 
• 5349-04-2 O¹,O⁶-diacetyl-O²,O⁴;O³,O⁵-dimethanediyl-D-iditol 
• 122174-81-6 O¹,O⁶-dibenzoyl-O²,O⁴;O³,O⁵-dimethanediyl-D-iditol 
• 122174-81-6 1,6-di-O-benzoyl-2,4:3,5-di-O-methylene-D-glucitol 

Relevant academic research and scientific papers

Polyamides and polyesters containing 2,4:3,5-di-O-methylene-L-idaroyl residues

Electrochemical oxidation of 2,4:3,5-di-O-methylene-D-gluconic acid in strong alkaline medium afforded a mixture of 2,4:3,5-di-O-methylene-D-glucaric acid 4 and 2,4:3,5-di-O-methylene-L-idaric acid 1 in a 1/8 ratio with a current efficiency of 53percent.Force-field calculations using Allinger's molecular mechanics program MM2p85 on 1 and 4 indicate that these cis-fused tetrahydro-dioxino-1,3-dioxin ring systems possess an O-inside conformation with a steric energy of 110.3 and 123.5 kJ*mol-1, respectively.Their conformation was confirmed by 400-MHz 1H- and 100-MHz 13C NMR measurements.A series of polycondensates were prepared by homogeneous solution polymerisation of 1 with an aromatic diol or aromatic diamine, which were analyzed by DSC and TGA.