73222-66-9Relevant academic research and scientific papers
Iridium-catalyzed enantioselective allyl-alkene coupling
Hamilton, James Y.,Sarlah, David,Carreira, Erick M.
supporting information, p. 3006 - 3009 (2014/03/21)
The direct Ir-catalyzed cross-coupling between branched, racemic allylic alcohols and simple olefins is described. This transformation is catalyzed by an Ir-(P,olefin) complex and proceeds with high site selectivity and excellent enantioselectivity. The m
Pd-catalyzed enantioselective allyl-allyl cross-coupling
Zhang, Ping,Brozek, Laura A.,Morken, James P.
supporting information; experimental part, p. 10686 - 10688 (2010/11/04)
The Pd-catalyzed cross-coupling of allylic carbonates and allylB(pin) is described. The regioselectivity of this reaction is sensitive to the bite angle of the ligand, with small-bite-angle ligands favoring the branched substitution product. This mode of
Oxovanadium-induced oxidative desilylation of allylic and benzylic silanes
Fujii, Takashi,Hirao, Toshikazu,Ohshiro, Yoshiki
, p. 5601 - 5604 (2007/10/02)
Cinnamyltrimethylsilane underwent desilylation via one-electron oxidation with VO(OEt)Cl2, which was applied to the cross-coupling with the less oxidizable allylic silanes to give the corresponding 1,5-hexadienes. Chlorination or aromatization
