76524-55-5Relevant academic research and scientific papers
Triflimide-catalyzed allyl-allyl cross-coupling: A metal-free allylic alkylation
Ding, Feiqing,William, Ronny,Wang, Fei,Liu, Xue-Wei
supporting information; experimental part, p. 8709 - 8711 (2012/10/08)
A highly efficient metal-free intermolecular C(sp3)-C(sp3) allyl-allyl cross-coupling protocol between allyl acetates and allyltrimethylsilanes, which proceeded smoothly in the presence of catalytic triflimide to form 1,5-dienes with good to excellent regioselectivity, has been developed.
Oxovanadium-induced oxidative desilylation of allylic and benzylic silanes
Fujii, Takashi,Hirao, Toshikazu,Ohshiro, Yoshiki
, p. 5601 - 5604 (2007/10/02)
Cinnamyltrimethylsilane underwent desilylation via one-electron oxidation with VO(OEt)Cl2, which was applied to the cross-coupling with the less oxidizable allylic silanes to give the corresponding 1,5-hexadienes. Chlorination or aromatization
ALLYLSTANNANES AS ELECTROFUGAL PARTNERS IN ALLYLIC ALKYLATION
Trost, Barry M.,Keinan, Ehud
, p. 2595 - 2598 (2007/10/02)
Unsymmetrical allyl-allyl couplings occur between allylstannanes and allyl acetates catalyzed by palladium(0) and a novel direct coupling of an allyl acetate in the presence of a distannane and a palladium(0) catalyst is also possible.
